Synthesis and Reactivity of β-ketosulfones

被引：4
作者：
Pena, Javier [1 ]
Moro, Rosalina F. [1 ]
Marcos, Isidro S. [1 ]
Diez, David [1 ]
机构：
[1] Univ Salamanca, Fac Ciencias Quim, Dept Quim Organ, E-37008 Salamanca, Spain
来源：
CURRENT ORGANIC CHEMISTRY | 2014年 / 18卷 / 23期
关键词：
Catalysis; ketosulfones; nazarov reagents; organometallic; reactivity; synthesis; DIELS-ALDER REACTIONS; RING-OPENING CYCLOISOMERIZATION; PALLADIUM-CATALYZED ARYLATION; ASYMMETRIC MANNICH REACTION; MICHAEL ADDITION-REACTIONS; ALPHA-SUBSTITUTED KETONES; FREE-RADICAL CYCLIZATION; SILICA SULFURIC-ACID; ONE-POT SYNTHESIS; C-H INSERTION;
D O I：
10.2174/1385272819666141009215154
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
beta-Ketosulfones are an important class of oxygen-containing extremely versatile compounds in organic chemistry. They attract the interest of chemists due to their interesting biological properties and synthetic applications on natural products and organic compounds. In this review we summarise the methods of synthesis and also the reactivity of beta-ketosulfones with the main focus on the position where the reaction takes place, including desulfonylation methodologies.
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页码：2972 / 3036
页数：65
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