Copper(I)-Induced Sulfenylation of H-Phosphonates, H-Phosphonites and Phosphine Oxides with Aryl/alkylsulfonylhydrazides as a Thiol Surrogate

被引：96
作者：
Kumaraswamy, Gullapalli [1 ,2 ]
Raju, Ragam [1 ]
机构：
[1] CSIR Indian Inst Chem Technol, Organ & Biomol Chem Div, Hyderabad 500607, Andhra Pradesh, India
[2] Acad Sci & Innovat Res AcSIR, New Delhi 110001, India
来源：
ADVANCED SYNTHESIS & CATALYSIS | 2014年 / 356卷 / 11-12期
关键词：
copper iodide; sulfenylation; sulfonylhydrazides; thiol surrogate; thiophosphates; SULFONYL HYDRAZIDES; TERMINAL ALKYNES; OXIDATION; AMINES; ARYL; DERIVATIVES; DIOXYGEN; ESTERS;
D O I：
10.1002/adsc.201400116
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
Aerobic dehydrogenative sulfenylation of H-phosphonites, and phosphine oxides with aryl/alkylsulfonyl hydrazides catalyzed by a sub-stoichiometric amount of copper iodide has been accomplished. This protocol is compatible with functional groups, and results in various thiophosphate derivatives in good to high yields.
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收藏
页码：2591 / 2598
页数：8
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