Ultrastable gold nanocatalyst supported by nanosized non-oxide substrate

被引：98
作者：
Yan, Wenfu [1 ]
Brown, Suree [1 ]
Pan, Zhengwei [1 ]
Mahurin, Shannon M. [1 ]
Overbury, Steven H. [1 ]
Dai, Sheng [1 ]
机构：
[1] Oak Ridge Natl Lab, Div Chem Sci, Oak Ridge, TN 37831 USA
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 22期
关键词：
gold; lanthanum; nanoparticles; oxidation; supported catalysts;
D O I：
10.1002/anie.200503808
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
(Figure Presented) Support system: The stability of a LaPO 4-supported Au nanocatalyst for CO oxidation exceeds that of Au nanocatalysts with oxide supports. Activation is achieved by high-temperature calcination under an oxidative atmosphere (see transmission electron microscopy image of crystalline Au nanoparticles on hexagonal LaPO4). The use of phosphates as supports for highly active gold catalysts opens up new routes in the search for ultrastable and sinter-resistant catalysts. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.
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收藏
页码：3614 / 3618
页数：5
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