The palladium(II)-decorated 22-tungsto-2-bismuthate(III), [Pd3(H2O)9Bi2W22O76]8-

被引：21

作者：

Bi, Li-Hua ^{[1
,2
]}

Dickman, Michael H. ^{[1
]}

Kortz, Ulrich ^{[1
]}

机构：

[1] Jacobs Univ, Sch Sci & Engn, D-28725 Bremen, Germany

[2] Jilin Univ, Coll Chem, Changchun 130012, Peoples R China

来源：

CRYSTENGCOMM | 2009年 / 11卷 / 06期

关键词：

POLYOXOMETALATE CLUSTERS; CRYSTAL-STRUCTURE; TUNGSTOSILICATE; HETEROPOLYMETALATE; ANALOG;

D O I：

10.1039/b820888c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The palladium(II) decorated tungstobismuthate(III) [Pd-3(H2O)(9)Bi2W22O76](8-) (1) has been prepared by a simple one-pot reaction of PdCl2 with Na-12[Bi2W22O74(OH)(2)] in aqueous acidic medium at pH 4.8. Polyanion 1 represents a rare example of a structurally characterized palladium-containing polyoxometalate.

引用

页码：965 / 966

页数：2

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