Study of transpiring fluid dynamics in supercritical water oxidation using a transparent reactor

被引:31
作者
Chen, Zhong [1 ,2 ]
Wang, Guangwei [1 ,2 ]
Mirza, Zakaria A. [1 ,2 ]
Yang, Shu [1 ,2 ]
Xu, Yuanjian [1 ,2 ]
机构
[1] Chinese Acad Sci, Chongqing Inst Green & Intelligent Technol, Chongqing 400714, Peoples R China
[2] Chinese Acad Sci, Key Lab Reservoir Aquat Environm, Chongqing 400714, Peoples R China
关键词
Fluid dynamics; Transpiring fluid; Transpiring wall reactor; Gas seal; Supercritical water oxidation; WALL REACTOR; POROUS REACTOR; SCWO REACTOR; DESTRUCTION; PARAMETERS; PRESSURES; EFFLUENTS; NITROGEN; OXYGEN; ARGON;
D O I
10.1016/j.supflu.2014.01.020
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The transpiring wall reactor (TWR) is considered to be one of the most promising reactors because it minimizes both corrosion and salt precipitation problems that seriously hinder the industrialization of supercritical water oxidation technologies. A transparent reactor is built to study the fluid dynamics of transpiring flow, which are the foundation of reactor design and optimization. The results showed that the transpiring flow is anisotropic with respect to the surface of the transpiring wall due to both the static pressure and viscous resistance. Finally, the novel idea of using air as the transpiring fluid instead of water is presented in an attempt to alleviate current TWR problems such as high energy consumption, high volume of pure water consumption, and temperature fluctuation in the reaction area. A series of experiments and theoretical derivations demonstrate that this novel idea is feasible. (C) 2014 Elsevier B.V. All rights reserved.
引用
收藏
页码:117 / 125
页数:9
相关论文
共 43 条
[1]  
Abeln J, 2007, J ADV OXID TECHNOL, V10, P169
[2]   Supercritical water oxidation (SCWO) using a transpiring wall reactor:: CFD simulations and experimental results of ethanol oxidation [J].
Abeln, J ;
Kluth, M ;
Böttcher, M ;
Sengpiel, W .
ENVIRONMENTAL ENGINEERING SCIENCE, 2004, 21 (01) :93-99
[3]   SuperCritical Water Oxidation (SCWO): A process for the treatment of industrial waste effluents [J].
Abeln, J ;
Kluth, M ;
Petrich, G ;
Schmieder, H .
HIGH PRESSURE RESEARCH, 2001, 20 (1-6) :537-+
[4]  
AHLUWALIA KS, 1996, Patent No. 5571424
[5]  
[Anonymous], 1995, US Patent, Patent No. [5384051, 5.384.051]
[6]  
[Anonymous], 2006, 40222006 BS EN ISO
[7]   Experimental study of the operational parameters of a transpiring wall reactor for supercritical water oxidation [J].
Bermejo, M. D. ;
Fdez-Polanco, E. ;
Cocero, M. J. .
JOURNAL OF SUPERCRITICAL FLUIDS, 2006, 39 (01) :70-79
[8]   Supercritical water oxidation: A technical review [J].
Bermejo, M. D. ;
Cocero, M. J. .
AICHE JOURNAL, 2006, 52 (11) :3933-3951
[9]   Effect of the transpiring wall on the behavior of a supercritical water oxidation reactor: Modeling and experimental results [J].
Bermejo, M. Dolores ;
Fdez-Polanco, Fernando ;
Cocero, M. Jose .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2006, 45 (10) :3438-3446
[10]   Operating results from supercritical water oxidation plants [J].
Crooker, PJ ;
Ahluwalia, KS ;
Fan, Z ;
Prince, J .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2000, 39 (12) :4865-4870