Template synthesis of conducting polyaniline composites based on honeycomb ordered polycarbonate film

被引：37

作者：

Lu, Yan ^{[1
]}

Ren, Yi ^{[2
]}

Wang, Li ^{[2
]}

Wang, Xudong ^{[2
]}

Li, Chenxi ^{[2
]}

机构：

[1] Tianjin Univ Technol, Inst Mat Phys, Minist Educ, Key Lab Display Mat & Photoelect Devices, Tianjin 300191, Peoples R China

[2] Nankai Univ, Inst Polymer Chem, Minist Educ, Key Lab Funct Polymer Mat, Tianjin 300071, Peoples R China

来源：

POLYMER | 2009年 / 50卷 / 09期

基金：

中国国家自然科学基金;

关键词：

Water-assisted method; PANI/PC composite film; Honeycomb structure; MICROPOROUS POLYETHYLENE FILMS; POLYMER-FILMS; MORPHOLOGY; MEMBRANES; FABRICATION;

D O I：

10.1016/j.polymer.2009.02.026

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

This paper describes the synthesis of polyaniline (PANI) layers by a simple one-step chemical oxidative polymerization, based on the surface of a honeycomb ordered porous polycarbonate (PC) film prepared via water-assisted method from PC/CHCl3 Solutions. The surface and cross-section morphology of the PANI/PC composite film was characterized by environmental scanning electron microscopy, indicating that the honeycomb ordered PC film plays the role as template in controlling the morphology of the PANI/PC composite film. The results of thermogravimetric analysis of the PANI/PC composite film showed higher thermal stability than PANI itself. The electrical conductivity of the PANI/PC composite film was also determined by the four-probe technique. (C) 2009 Elsevier Ltd. All rights reserved.

引用

页码：2035 / 2039

页数：5

共 20 条

[1] Mesoscopic and submicroscopic patterning in thin polymer films: Impact of the solvent [J].

Bormashenko, E ;

Pogreb, R ;

Stanevsky, O ;

Bormashenko, Y ;

Tamir, S ;

Cohen, R ;

Nunberg, M ;

Gaisin, VZ ;

Gorelik, M ;

Gendelman, OV .

MATERIALS LETTERS, 2005, 59 (19-20) :2461-2464

[2] Self-assembled honeycomb polycarbonate films deposited on polymer piezoelectric substrates and their applications [J].

Bormashenko, E ;

Pogreb, R ;

Stanevsky, O ;

Bormashenko, Y ;

Socol, Y ;

Gendelman, O .

POLYMERS FOR ADVANCED TECHNOLOGIES, 2005, 16 (04) :299-304

[3] Photoelectrochemistry of polyaniline supported in a microporous cellulose acetate membrane [J].

das Neves, S ;

De Paoli, MA .

SYNTHETIC METALS, 1998, 96 (01) :49-54

[4] Continuous convective assembling of fine particles into two-dimensional arrays on solid surfaces [J].

Dimitrov, AS ;

Nagayama, K .

LANGMUIR, 1996, 12 (05) :1303-1311

[5] Thermochemical and deformational stability of microporous polyethylene films with polyaniline layer [J].

Elyashevich, GK ;

Terlemezyan, L ;

Kuryndin, IS ;

Lavrentyeva, VK ;

Mokreva, P ;

Rosova, EY ;

Sazanov, YN .

THERMOCHIMICA ACTA, 2001, 374 (01) :23-30

[6] Properties of polymer conducting thin layers on the surface of microporous polyethylene films [J].

Elyashevich, GK ;

Lavrentyev, VK ;

Kuryndin, IS ;

Rosova, EY .

SYNTHETIC METALS, 2001, 119 (1-3) :277-278

[7]

Elyashevich GK, 1997, J APPL POLYM SCI, V64, P2665

[8] Polymer films with a self-organized honeycomb morphology [J].

Francois, B ;

Pitois, O ;

Francois, J .

ADVANCED MATERIALS, 1995, 7 (12) :1041-&

[9] Studies on SLS doped polyaniline and its blend with PC [J].

Jeevananda, T ;

Siddaramaiah ;

Annadurai, V ;

Somashekar, R .

JOURNAL OF APPLIED POLYMER SCIENCE, 2001, 82 (02) :383-388

[10] TEMPLATE SYNTHESIS OF ORGANIC MICROTUBULES [J].

MARTIN, CR ;

VANDYKE, LS ;

CAI, ZH ;

LIANG, WB .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (24) :8976-8977

← 1 2 →