Preparation and characterization of nylon 6 11 copolymer

被引：33
|
作者：
Wang, Biao-Bing [1 ]
Hu, Guo-Sheng [1 ]
Zhao, Xin [1 ]
Gao, Feng-Zhen [1 ]
机构：
[1] N Univ China, Inst Marcromol & Bioengn, Taiyuan 030051, Peoples R China
来源：
MATERIALS LETTERS | 2006年 / 60卷 / 21-22期
关键词：
copolyamide; 6; 11; preparation; characterization; NONISOTHERMAL CRYSTALLIZATION KINETICS; MECHANICAL-PROPERTIES; MORPHOLOGY; CRYSTALS;
D O I：
10.1016/j.matlet.2006.01.076
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
A new copolyamide, nylon 6 11, was prepared by hydrolytic polymerization and melt polycondensation and characterized by means of intrinsic viscosity, Fourier transform infrared (FTIR) spectroscopy and differential scanning calorimetry (DSC) in this paper. It was found that the intrinsic viscosity of nylon 6 11 copolymer was influenced by the caprolactam content as well as the copolymerization time under vacuum. However, the incorporation of caprolactam into nylon 11 chains did not transform the crystal phase of nylon 11. The results of DSC demonstrated that a random copolyamide was formed during copolymerization of aminoundecanoic acid with caprolactam. (c) 2006 Elsevier B.V All rights reserved.
引用
收藏
页码：2715 / 2717
页数：3
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