Water-soluble hybrid materials based on {Mo6X8}4+ (X = Cl, Br, I) cluster complexes and sodium polystyrene sulfonate

被引：45

作者：

Svezhentseva, Ekaterina V. ^{[1
,2
]}

Solovieva, Anastasiya O. ^{[3
]}

Vorotnikov, Yuri A. ^{[1
]}

Kurskaya, Olga G. ^{[4
]}

Brylev, Konstantin A. ^{[1
,2
]}

Tsygankova, Alphiya R. ^{[1
,2
]}

Edeleva, Mariya V. ^{[5
]}

Gyrylova, Svetlana N. ^{[4
]}

Kitamura, Noboru ^{[6
]}

Efremova, Olga A. ^{[7
]}

Shestopalov, Michael A. ^{[1
,2
,3
,4
]}

Mironov, Yuri V. ^{[1
,2
]}

Shestopalov, Alexander M. ^{[4
]}

机构：

[1] Nikolaev Inst Inorgan Chem SB RAS, 3 Acad Lavrentiev Ave, Novosibirsk 630090, Russia

[2] Novosibirsk State Univ, 2 Pirogova Str, Novosibirsk 630090, Russia

[3] Sci Inst Clin & Expt Lymphol, 2 Timakova Str, Novosibirsk 630060, Russia

[4] Res Inst Expt & Clin Med, 2 Timakova Str, Novosibirsk 630060, Russia

[5] Vorozhtsov Novosibirsk Inst Organ Chem SB RAS, 9 Acad Lavrentiev Ave, Novosibirsk 630090, Russia

[6] Hokkaido Univ, Dept Chem, Fac Sci, Sapporo, Hokkaido 0600810, Japan

[7] Univ Hull, Dept Chem, Cottingham Rd, Kingston Upon Hull HU6 7RX, N Humberside, England

来源：

NEW JOURNAL OF CHEMISTRY | 2017年 / 41卷 / 04期

基金：

俄罗斯科学基金会; 日本学术振兴会;

关键词：

MOLYBDENUM CLUSTER; LUMINESCENCE PROPERTIES; LIGANDS; INCLUSION; POLYMER; MIL-101;

D O I：

10.1039/c6nj03469a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The development of water-soluble forms of octahedral molybdenum clusters {Mo6X8}(4+) (X = Cl, Br, I) is strongly motivated by the tremendous potential that these complexes have for biological applications, namely as agents for bioimaging and photodynamic therapy. In this work, we report the first water-soluble hybrid materials, which represent sodium polystyrene sulfonate doped by molybdenum clusters, and the evaluation of their photophysical and biological properties (dark and photoinduced cytotoxicity and cellular uptake) with the use of cervical cancer (HeLa) and human epidermoid larynx carcinoma (Hep-2) cell-lines as models.

引用

页码：1670 / 1676

页数：7

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