A coordination polymer containing inorganic buckybowl analogues

被引：54

作者：

Wu, Tao ^{[1
]}

Chen, Miao ^{[1
]}

Li, Dan ^{[1
]}

机构：

[1] Shantou Univ, Dept Chem, Shantou 515063, Guangdong, Peoples R China

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2006年 / 11期

关键词：

inorganic buckybowl analogues; tetrazoles; sharpless' cycloaddition; copper; coordination polymers;

D O I：

10.1002/ejic.200501105

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two photoluminescent coordination polymers, {[Cu-10(mu(3)-Mtta)(3)(mu(4)-Mtta)(7)]center dot 2H(2)O}(n) (1), containing 2-D wavy motifs with inorganic buckybowl analogues, and [Cu-5(mu(3)-Mtta)(2)(mu(4)-Mtta)(3)(NH3)(2)](n) (2, Mtta = 5-methyl tetrazolate), were obtained by the control of solvents and auxiliary complexing agent. The ligand Mtta is a likely candidate for the construction of metal-organic, fullerene-like molecules. The luminescent properties of 1 and 2 are discussed.

引用

页码：2132 / 2135

页数：4