A coordination polymer containing inorganic buckybowl analogues

被引：54
作者：
Wu, Tao [1 ]
Chen, Miao [1 ]
Li, Dan [1 ]
机构：
[1] Shantou Univ, Dept Chem, Shantou 515063, Guangdong, Peoples R China
来源：
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2006年 / 11期
关键词：
inorganic buckybowl analogues; tetrazoles; sharpless' cycloaddition; copper; coordination polymers;
D O I：
10.1002/ejic.200501105
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two photoluminescent coordination polymers, {[Cu-10(mu(3)-Mtta)(3)(mu(4)-Mtta)(7)]center dot 2H(2)O}(n) (1), containing 2-D wavy motifs with inorganic buckybowl analogues, and [Cu-5(mu(3)-Mtta)(2)(mu(4)-Mtta)(3)(NH3)(2)](n) (2, Mtta = 5-methyl tetrazolate), were obtained by the control of solvents and auxiliary complexing agent. The ligand Mtta is a likely candidate for the construction of metal-organic, fullerene-like molecules. The luminescent properties of 1 and 2 are discussed.
引用
收藏
页码：2132 / 2135
页数：4
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