Phosphate-modified graphitic C3N4 as efficient photocatalyst for degrading colorless pollutants by promoting O2 adsorption

被引:98
作者
Liu, Chong [1 ,2 ]
Jing, Liqiang [1 ]
He, Lumei [1 ]
Luan, Yunbo [1 ]
Li, Chengming [1 ]
机构
[1] Heilongjiang Univ, Sch Chem & Mat Sci, Key Lab Funct Inorgan Mat Chem, Minist Educ, Harbin 150080, Peoples R China
[2] Heilongjiang Univ Sci & Technol, Coll Environm & Chem Engn, Harbin 150027, Peoples R China
关键词
CARBON NITRIDE SOLIDS; VISIBLE-LIGHT; PHOTOGENERATED CHARGES; ELECTRONIC-STRUCTURE; TIO2; WATER; NANOPARTICLES; MORPHOLOGY;
D O I
10.1039/c3cc47398h
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The photocatalytic activity for degrading gas-phase acetaldehyde and liquid-phase phenol by graphitic carbon nitride could be greatly improved after modification with phosphoric acid, which is attributed to the clear increase in adsorbed O-2 which prolongs the lifetime and enhances the separation of photogenerated charge carriers. This is based on O-2 temperature-programmed desorption curves, steady-state surface photovoltage spectra, and time-resolved surface photovoltage responses.
引用
收藏
页码:1999 / 2001
页数:3
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