Titanium dioxide-molybdenum disulfide for photocatalytic degradation of methylene blue

被引:36
作者
Ibukun, Olaniyan [1 ]
Evans, Prescott E. [2 ]
Dowben, Peter A. [2 ]
Jeong, Hae Kyung [1 ,3 ]
机构
[1] Daegu Univ, Inst Basic Sci, Dept Phys, Gyongsan 712714, South Korea
[2] Univ Nebraska, Dept Phys & Astron, Lincoln, NE 68588 USA
[3] Daegu Univ, Inst Ind & Tech, Dept Mat Energy Sci & Engn, Gyongsan 712714, South Korea
基金
新加坡国家研究基金会;
关键词
Titanium dioxide; Molybdenum disulfide; Photocatalysis; Methylene blue; VISIBLE-LIGHT; MOS2; TIO2; DYE; NANOSTRUCTURES; CRYSTAL; ORANGE;
D O I
10.1016/j.chemphys.2019.110419
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Photocatalytic degradation of methylene blue (MB) was performed using titanium dioxide and molybdenum disulfide (TiO2-MoS2) composites. TiO2-MoS2 composites were synthesized using the sol-gel method. By weight, the ratio of MoS2 to TiO2 was varied from 3:5 to 9:5. The composites showed better photocatalytic degradation of MB compared to pure TiO2 under irradiation of ultraviolet light, and the 7:5 ratio (which was labelled S3) provides the best photodegradation efficiency for MB. TiO2 degraded MB under 180 min while S3 degraded MB under 80 min. The photocurrent response of pure TiO2 was 0.55 mu A, but was increased to 20.08 mu A (S3) after the addition of MoS2. The electrochemical results reveal that the introduction of MoS2 into TiO2 improves the electronic conductivity and the lifetime of the photogenerated charge carriers, resulting in higher photocatalytic behavior in the decomposition of methylene blue.
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页数:6
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