Synthesis and reactions of organic compounds with a nitrogen atom .12. Toluenesulfonamidation of (+)-2-carene and synthesis of amines and aminoalcohols of the carane group

被引：0

作者：

Uzarewicz, A

Scianowski, J

机构：

来源：

POLISH JOURNAL OF CHEMISTRY | 1997年 / 71卷 / 01期

关键词：

toluenesulfonamidation; allylic amines; Birch reduction; hydroboration-oxidation; synthesis;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Toluenesulfonamidation of (+)-2-carene 2 afforded: 4-methyl-N-trans-(2-caren-4-yl) benzenesulfonamide 3 and 4-methyl-N-(2-caren-10-yl)benzenesulfonamide 4, which were converted by the reduction with sodium in liquid ammonia to: (-)-trans-4-amino-2-carene 5 and (+)-10-amino-2-carene 6. Hydroboration-oxidation of amines 5 and 6 afforded aminoalcohols 7, 8 and 9.

引用

页码：48 / 51

页数：4

共 8 条

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