Determination of the nitrogen gas transmission rate (N2GTR) of ethylene vinyl alcohol copolymer, using a newly developed permeation measurement system

被引：5
|
作者：
Maes, Caroline [1 ]
te Molder, Maarten [2 ]
Luyten, Wout [3 ]
Herremans, Geert [3 ]
Winckelmans, Naomi [3 ]
Peeters, Roos [1 ]
Carleer, Robert [4 ]
Buntinx, Mieke [1 ]
机构：
[1] Hasselt Univ, Packaging Technol Ctr, IMO IMOMEC, Wetenschapspk 27, B-3590 Diepenbeek, Belgium
[2] Intersci BV, Tinstr 16, NL-4823 AA Breda, Netherlands
[3] Kuraray Eval Europe NV, Nieuwe Weg 1,Bus 10, B-2070 Zwijndrecht, Belgium
[4] Hasselt Univ, IMO IMOMEC Appl & Analyt Chem, Agoralaan Bldg D, B-3590 Diepenbeek, Belgium
来源：
POLYMER TESTING | 2021年 / 93卷
关键词：
Ethylene vinyl alcohol copolymer; EVOH; Nitrogen gas transmission rate; Permeability; Barrier properties; CAPILLARY COLUMNS; PERMEABILITY; FILMS; COMPONENTS; OXYGEN; VAPOR; WATER;
D O I：
10.1016/j.polymertesting.2020.106979
中图分类号：
TB3 [工程材料学];
学科分类号：
0805 ; 080502 ;
摘要：
The oxygen (O-2) barrier properties of ethylene vinyl alcohol copolymer (EVOH) have been widely investigated, but for other gases the available data are usually limited to dry conditions due to limitations in measurement equipment. Innovative permeation measurement systems with low detection limits are required to determine the gas transmission rate (GTR) of other gases, such as nitrogen (N-2) at varying temperature and relative humidity. This study presents the design and development of a versatile permeation measurement system consisting of two subsystems: a permeation system and a detection system using gas chromatography and a pulsed discharge helium ionization detector. The measured O(2)GTR and N(2)GTR of three different 20 mu m-EVOH grades containing 32, 44 and 48 mol% ethylene are in good accordance to those obtained on validated MOCON OX-TRAN (R) modules and a GC-differential pressure method respectively, with differences within the analytical uncertainty of each method.
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页数：14
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