Comparison of activated carbons prepared by one-step and two-step chemical activation process based on cotton stalk for supercapacitors application

被引:113
作者
Cheng, Jie [1 ]
Hu, Sheng-Chun [2 ]
Sun, Guo-Tao [3 ]
Kang, Kang [3 ]
Zhu, Ming-Qiang [3 ]
Geng, Zeng-Chao [1 ]
机构
[1] Northwest A&F Univ, Coll Nat Resources & Environm, Yangling 712100, Shaanxi, Peoples R China
[2] Northwest A&F Univ, Coll Forestry, Yangling 712100, Shaanxi, Peoples R China
[3] Northwest A&F Univ, Coll Mech & Elect Engn, Yangling 712100, Shaanxi, Peoples R China
关键词
Cotton stalk; Activated carbon; Supercapacitor; Electrochemistry; Specific capacitance; POROUS CARBON; ENERGY-STORAGE; RICE HUSK; WOOD; PRETREATMENT; POLLUTANT; POLYMER; FIBERS;
D O I
10.1016/j.energy.2020.119144
中图分类号
O414.1 [热力学];
学科分类号
摘要
Cotton stalk (CS) was successively treated via one-step and two-step activation process to synthesize activated carbons (ACs), which were utilized for electrode substances in the supercapacitors. The results showed that the activated carbon generated via one-step activation process at 600 degrees C demonstrate excellent specific surface area (1342.93 m(2)/g), which accompanied with high proportion of mesopores pore volume (97%) than those from two-step activation process. Moreover, a large specific capacitance of 338 F/g was observed in the AC that generated at the activated temperature of 600 degrees C via one-step activation process. The biomass-derived ACs presented an overall better electrochemistry characteristic than those from biochar-derived ACs, suggesting that the electrochemical performances of activated carbon generated from biomass-derived were better than those from biochar-derived. The data proved that the as-prepared ACs are promising materials for advanced energy storage, which is beneficial for value-added and industrial supercapacitors application of cotton stalk activated carbons. (C) 2020 Elsevier Ltd. All rights reserved.
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页数:15
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