Electrochemiluminescence of cyclometalated iridium (III) complexes

被引：43

作者：

Haghighatbin, Mohammad A. ^{[1
]}

Laird, Sarah E. ^{[2
]}

Hogan, Conor F. ^{[1
]}

机构：

[1] La Trobe Univ, Dept Chem & Phys, La Trobe Inst Mol Sci, Melbourne, Vic 3086, Australia

[2] Univ Strasbourg, Inst Sci & Ingn Supramol, Strasbourg, France

来源：

CURRENT OPINION IN ELECTROCHEMISTRY | 2018年 / 7卷

基金：

澳大利亚研究理事会;

关键词：

ON-A-MOLECULE; ELECTROGENERATED CHEMILUMINESCENCE; ENHANCED ELECTROCHEMILUMINESCENCE;

D O I：

10.1016/j.coelec.2018.03.026

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The advent of highly emissive cyclometalated iridium complexes has injected new vigour into the field of electrochemiluminescence (ECL), with these materials now beginning to challenge the dominance of ruthenium diimine complexes for ECL applications. The promise of iridium-based electrochemiluminophores lies not only in their enhanced photophysical properties but in the relative ease with which their emission wavelengths and redox potentials can be tailored. However, innovative approaches and better understanding are required to tackle the challenges which sometimes arise associated with their susceptibility to quenching, especially in aqueous media.

引用

页码：216 / 223

页数：8

共 36 条

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