Effective Heat Dissipation from Color-Converting Plates in High-Power White Light Emitting Diodes by Transparent Graphene Wrapping

被引:41
作者
Kim, Eden [1 ,2 ]
Shim, Hyeon Woo [4 ]
Unithrattil, Sanjith [1 ,2 ]
Kim, Yoon Hwa [1 ,2 ]
Choi, Hojin [4 ]
Ahn, Ki-Jin [4 ]
Kwak, Joon Seop [5 ]
Kim, Sungmin [3 ,4 ]
Yoon, Hyeonseok [3 ,4 ]
Bin Im, Won [1 ,2 ]
机构
[1] Chonnam Natl Univ, Sch Mat Sci & Engn, Gwangju 61186, South Korea
[2] Chonnam Natl Univ, Optoelect Convergence Res Ctr, Gwangju 61186, South Korea
[3] Chonnam Natl Univ, Alan G MacDiarmid Energy Res Inst, Sch Polymer Sci & Engn, Gwangju 61186, South Korea
[4] Chonnam Natl Univ, Dept Polymer Engn, Grad Sch, Gwangju 61186, South Korea
[5] Sunchon Natl Univ, Dept Printed Elect Engn, Jeonnam 57922, South Korea
基金
新加坡国家研究基金会;
关键词
LEDs; graphene; heat dissipation; cellular automata; THERMAL-CONDUCTIVITY; RAMAN-SPECTRA; PHOSPHOR; TEMPERATURE; DEPENDENCE;
D O I
10.1021/acsnano.5b06734
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
We have developed a hybrid phosphor-in-glass plate (PGP) for application in a remote phosphor configuration of high-power white light emitting diodes (WLEDs), in which single-layer graphene was used to modulate the thermal characteristics of the PGP. The degradation of luminescence in the PGP following an increase in temperature could be prevented by applying single-layer graphene. First, it was observed that the emission intensity of the PGP was enhanced by about 20% with graphene wrapping. Notably, the surface temperature of the graphene-wrapped PGP (G-PGP) was found to be higher than that of the bare PGP, implying that the graphene layer effectively acted as a heat dissipation medium on the PGP surface to reduce the thermal quenching of the constituent phosphors. Moreover, these experimental observations were clearly verified through a two-dimensional cellular automata simulation technique and the underlying mechanisms were analyzed. As a result, the proposed G-PGP was found to be efficient in maintaining the luminescence properties of the WLED, and is a promising development in high power WLED applications. This research could be further extended to generate a new class of optical or optoelectronic materials with possible uses in a variety of applications.
引用
收藏
页码:238 / 245
页数:8
相关论文
共 36 条
[1]   Tuning the Luminescence of Phosphors: Beyond Conventional Chemical Method [J].
Bai, Gongxun ;
Tsang, Ming-Kiu ;
Hao, Jianhua .
ADVANCED OPTICAL MATERIALS, 2015, 3 (04) :431-462
[2]   Superior thermal conductivity of single-layer graphene [J].
Balandin, Alexander A. ;
Ghosh, Suchismita ;
Bao, Wenzhong ;
Calizo, Irene ;
Teweldebrhan, Desalegne ;
Miao, Feng ;
Lau, Chun Ning .
NANO LETTERS, 2008, 8 (03) :902-907
[3]   Synthesis and Spectroscopic Properties of Nano-scale Y2O3:Nd3+ Phosphors [J].
Bilir, G. ;
Ozen, G. ;
Collins, J. ;
Di Bartolo, B. .
LUMINESCENCE AND DISPLAY MATERIALS: FUNDAMENTALS AND APPLICATIONS, 2013, 50 (41) :1-7
[4]   Thermal Transport in Suspended and Supported Monolayer Graphene Grown by Chemical Vapor Deposition [J].
Cai, Weiwei ;
Moore, Arden L. ;
Zhu, Yanwu ;
Li, Xuesong ;
Chen, Shanshan ;
Shi, Li ;
Ruoff, Rodney S. .
NANO LETTERS, 2010, 10 (05) :1645-1651
[5]   Temperature dependence of the Raman spectra of graphene and graphene multilayers [J].
Calizo, I. ;
Balandin, A. A. ;
Bao, W. ;
Miao, F. ;
Lau, C. N. .
NANO LETTERS, 2007, 7 (09) :2645-2649
[6]   Graphene-Based Nanomaterials: Synthesis, Properties, and Optical and Optoelectronic Applications [J].
Chang, Haixin ;
Wu, Hongkai .
ADVANCED FUNCTIONAL MATERIALS, 2013, 23 (16) :1984-1997
[7]   Advances in transparent glass-ceramic phosphors for white light-emitting diodes-A review [J].
Chen, Daqin ;
Xiang, Weidong ;
Liang, Xiaojuan ;
Zhong, Jiasong ;
Yu, Hua ;
Ding, Mingye ;
Lu, Hongwei ;
Ji, Zhenguo .
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2015, 35 (03) :859-869
[8]   Substrate coupling suppresses size dependence of thermal conductivity in supported graphene [J].
Chen, Jie ;
Zhang, Gang ;
Li, Baowen .
NANOSCALE, 2013, 5 (02) :532-536
[9]   Thermal contact resistance between graphene and silicon dioxide [J].
Chen, Z. ;
Jang, W. ;
Bao, W. ;
Lau, C. N. ;
Dames, C. .
APPLIED PHYSICS LETTERS, 2009, 95 (16)
[10]   Enhanced fluorescence and heat dissipation of calcium titanate red phosphor based on silver coating [J].
Chen, Zhenhua ;
Qin, Xinxin ;
Zhang, Qinghong ;
Li, Yaogang ;
Wang, Hongzhi .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2015, 459 :44-52