Effect of equal-channel angular pressing and aging on corrosion behavior of ZK60 Mg alloy

被引:41
作者
Li, Xin [1 ]
Jiang, Jing-hua [2 ]
Zhao, Yong-hao [1 ]
Ma, Ai-bin [2 ]
Wen, Dao-jing [1 ]
Zhu, Yun-tian [1 ,3 ]
机构
[1] Nanjing Univ Sci & Technol, Sch Mat Sci & Engn, Nanjing 210094, Jiangsu, Peoples R China
[2] Hohai Univ, Coll Mech & Mat, Nanjing 210098, Jiangsu, Peoples R China
[3] N Carolina State Univ, Dept Mat Sci & Engn, Raleigh, NC 27695 USA
关键词
ZK60 Mg alloy; equal-channel angular pressing; aging; corrosion resistance; fine-grains; ELECTROCHEMICAL IMPEDANCE SPECTROSCOPY; THIN ELECTROLYTE LAYERS; AZ91D MAGNESIUM ALLOY; MECHANICAL-PROPERTIES; ATMOSPHERIC CORROSION; GRAIN-REFINEMENT; ZR ALLOY; MICROSTRUCTURE; METALS; ECAP;
D O I
10.1016/S1003-6326(15)64038-9
中图分类号
TF [冶金工业];
学科分类号
0806 ;
摘要
Commercial ZK60 Mg alloy was processed by multi-pass equal-channel angular pressing (ECAP) and subsequent aging to investigate the effect of grain refinement and second-phase redistribution on its corrosion behavior. Electrochemical tests show that the fine-grained samples after more ECAP passes have higher corrosion current densities (J(corr)) in the polarization curves, lower charge-transfer resistance (R-t) values in the EIS plots. The severe plastic deformation decreases the alloy corrosion resistance besides the well-known strengthening and toughening. Scanning Kelvin probe (SKP) measurement shows that the anodic and cathode sites are homogeneously distributed on the surface of the fine-grained alloy, which inhibits localized corrosion. The SKP potential, having linear relationship with the corrosion potential (phi(corr)), decreases with increasing the ECAP pass. Furthermore, the post-ECAP aging can slightly improve the corrosion resistance of the fine-grained ZK60 Mg alloy and enhance the comprehensive performances, due to the stress relief and uniform distribution of second-phase particles.
引用
收藏
页码:3909 / 3920
页数:12
相关论文
共 29 条
[1]   Studies on the influence of chloride ion and pH on the corrosion and electrochemical behaviour of AZ91D magnesium alloy [J].
Ambat, R ;
Aung, NN ;
Zhou, W .
JOURNAL OF APPLIED ELECTROCHEMISTRY, 2000, 30 (07) :865-874
[2]   Corrosion resistance of ultra fine-grained Ti [J].
Balyanov, A ;
Kutnyakova, J ;
Amirkhanova, NA ;
Stolyarov, VV ;
Valiev, RZ ;
Liao, XZ ;
Zhao, YH ;
Jiang, YB ;
Xu, HF ;
Lowe, TC ;
Zhu, YT .
SCRIPTA MATERIALIA, 2004, 51 (03) :225-229
[3]  
Cao C N, 1990, ELECTROCHIM ACTA, V35, P837
[5]   Grain refinement of magnesium alloys processed by severe plastic deformation [J].
Chen, Yong-jun ;
Wang, Qu-dong ;
Lin, Jin-bao ;
Liu, Man-ping ;
Hjelen, Jarle ;
Roven, Hans J. .
TRANSACTIONS OF NONFERROUS METALS SOCIETY OF CHINA, 2014, 24 (12) :3747-3754
[6]  
[董超芳 DONG Chao-fang], 2009, [北京科技大学学报, Journal of University Science and Technology Beijing], V31, P878
[7]  
Hamu GB., 2009, J Alloys Compd, V468, P222, DOI [10.1016/j.jallcom.2008.01.084, DOI 10.1016/J.JALLCOM.2008.01.084]
[8]   Microstructure and mechanical properties of ZK60 alloy processed by two-step equal channel angular pressing [J].
He, Yunbin ;
Pan, Qinglin ;
Qin, Yinjiang ;
Liu, Xiaoyan ;
Li, Wenbin ;
Chiu, Yulung ;
Chen, John J. J. .
JOURNAL OF ALLOYS AND COMPOUNDS, 2010, 492 (1-2) :605-610
[9]   Corrosion of pure Mg as a function of grain size and processing route [J].
Hoog, C. op't ;
Birbilis, N. ;
Estrin, Y. .
ADVANCED ENGINEERING MATERIALS, 2008, 10 (06) :579-582
[10]   ANODIC OXIDATION OF ALUMINUM, CHROMIUM, HAFNIUM, NIOBIUM, TANTALUM, TITANIUM, VANADIUM, AND ZIRCONIUM AT VERY LOW CURRENT DENSITIES [J].
JOHANSEN, HA ;
ADAMS, GB ;
VANRYSSELBERGHE, P .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1957, 104 (06) :339-346