Zinc(II) and Cadmium(II) Coordination Polymers Based on 5-Hydroxylisophthalate and Semi-rigid Bis(imidazole) Ligands: Syntheses, Structural and Photoluminescent Properties

被引：3

作者：

Zhao, Jun ^{[1
]}

Wang, Yenan ^{[1
]}

Xia, Wei ^{[1
]}

Dong, Wenwen ^{[1
]}

Li, Dongsheng ^{[1
]}

机构：

[1] China Three Gorges Univ, Inst Mat Res, Coll Mech & Mat Engn, Yichang, Peoples R China

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2014年 / 640卷 / 8-9期

基金：

中国国家自然科学基金;

关键词：

Coordination polymer; 5-Hydroxylisophthalic acid; X-ray diffraction; Topology; Luminescence; METAL-ORGANIC FRAMEWORKS; MAGNETIC-PROPERTIES; CRYSTAL-STRUCTURES; IMIDAZOLATE FRAMEWORKS; NITRIC-OXIDE; BENZENEDICARBOXYLATE; LUMINESCENT; TOPOLOGY; SEPARATION; COMPLEXES;

D O I：

10.1002/zaac.201300488

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two new coordination polymers, namely, [Zn(bdc)(mbix)](n) (1) and {[Cd-2(bdc)(2)(mbix)(2)]H2O}(n) (2) [H(2)bdc = 5-hydroxylisophthalic acid, mbix = 1,3-bis(imidazol-1-yl-methyl) benzene], were obtained under hydrothermal conditions and characterized by elemental analysis, IR spectroscopy, as well as powder-and single-crystal X-ray diffraction. Compound 1 exhibits a 2D puckered layer with 4,4) topology, which is further interconnected by hydrogen bonding interactions leading to a 3D supramolecular architecture. Compound 2 features a 5-connected 3D network with bnn (4(6).6(4)) topology based on the dinuclear Cd-II subunits. In addition, solid-state properties such as thermal stabilities and photoluminescent properties of compounds 1 and 2 were also investigated.

引用

页码：1665 / 1669

页数：5

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