Corrosion behavior of sintered CeNdFeB magnets in different solutions

被引：26
作者：
Bi, Mengxue [1 ,2 ]
Xu, Cheng [1 ]
Wattoo, Abdul Ghafar [1 ]
Bagheri, Robabeh [1 ]
Chen, Yanxia [2 ]
Mao, Shoudong [3 ]
Lv, Zhongshan [4 ]
Yang, Lijing [1 ]
Song, Zhenlun [1 ]
机构：
[1] Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, Zhejiang Prov Key Lab Magnet Mat & Applicat Techn, CAS Key Lab Magnet Mat & Devices, Ningbo 315201, Zhejiang, Peoples R China
[2] Univ Sci & Technol China, Nano Sci & Technol Inst, Hefei 230026, Peoples R China
[3] Hangzhou Permanent Magnet Grp Co Ltd, Hangzhou 311200, Zhejiang, Peoples R China
[4] Ningbo Shuo Teng New Mat Co Ltd, Cixi 315301, Peoples R China
来源：
JOURNAL OF ALLOYS AND COMPOUNDS | 2017年 / 703卷
关键词：
CeNdFeB magnets; Electrochemical; Morphology; Corrosion behavior; FE-B MAGNETS; NDFEB PERMANENT-MAGNET; MELT-SPUN; ND; RESISTANCE; CE; MICROSTRUCTURE; SUBSTITUTION; ACID; DY;
D O I：
10.1016/j.jallcom.2017.01.347
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The capability of CeNdFeB as a substitute for NdFeB is of considerable interest due to its cost effectiveness and fascinating magnetic properties. In this paper, we have systematically investigated the corrosion behavior of the sintered CeNdFeB magnets in alkaline and acidic media in order to evaluate their commercial viability. Electrochemical and immersion tests have been conducted using sintered CeNdFeB magnets with different amounts of Ce (0.0 wt%, 29.6 wt%, 44.6 wt%, 54.8 wt%) as substitution of Nd in different concentrations of sodium hydroxide (NaOH), nitric acid (HNO3), hydrochloric acid (HCl), sulfuric acid (H2SO4), and oxalic acid (H2C2O4). We have found that the sintered CeNdFeB magnets exhibit passive behavior and the corrosion rate decreases in NaOH and H2C2O4 solutions by comparison with sintered NdFeB magnets. When exposed in strong acids, the sintered CeNdFeB has comparable corrosion properties with sintered NdFeB in HNO3 solution and lower anticorrosion properties in HCl and H2SO4 solutions. (C) 2017 Elsevier B.V. All rights reserved.
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收藏
页码：232 / 241
页数：10
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