Perfect balance harmony in Ba2NO3(OH)3: a beryllium-free nitrate as a UV nonlinear optical material

被引：150

作者：

Dong, Xuehua ^{[1
]}

Huang, Ling ^{[2
]}

Liu, Qingyu ^{[1
]}

Zeng, Hongmei ^{[1
]}

Lin, Zhien ^{[1
]}

Xu, Dingguo ^{[1
]}

Zou, Guohong ^{[1
]}

机构：

[1] Sichuan Univ, Coll Chem, Chengdu 610064, Sichuan, Peoples R China

[2] Sichuan Normal Univ, Coll Chem & Mat Sci, Chengdu 610068, Sichuan, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2018年 / 54卷 / 45期

基金：

中国国家自然科学基金;

关键词：

BOND-VALENCE PARAMETERS; 2ND-HARMONIC GENERATION; FLUORIDE CARBONATE; CRYSTAL; DESIGN; BORATE; APPROXIMATION;

D O I：

10.1039/c8cc03007c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A promising UV nonlinear optical material, beryllium-free nitrate Ba2NO3(OH)(3), has been synthesized via modified high-temperature solid state reactions in a self-made high-pressure apparatus which exhibits a perfect balance of a large second harmonic generation coefficient, an appropriate birefringence for phase matching, a short UV absorption cutoff edge and physicochemical stabilities.

引用

页码：5792 / 5795

页数：4

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