Synthesis, Structure and Magnetic Property of a New MOF with Triazolate and Azido Heterobridges

被引：0
作者：
Wang Ye [1 ]
Zhao Hong [1 ]
Liu Zhong-Yi [1 ]
Yang En-Cui [1 ]
Zhao Xiao-Jun [1 ]
机构：
[1] Tianjin Normal Univ, Coll Chem, Minist Educ,Key Lab Inorgan Organ Hybrid Funct Ma, Tianjin Key Lab Struct & Performance Funct Mol, Tianjin 300387, Peoples R China
来源：
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2014年 / 33卷 / 08期
关键词：
triazolate; azide; magnetism; crystal structure; SPIN-CANTED ANTIFERROMAGNETISM; HYDROTHERMAL SYNTHESIS; CRYSTAL-STRUCTURES; LIGANDS; FRAMEWORKS; COMPLEXES; BRIDGES; CHAINS;
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new magnetic MOF with cyclic triazolate and linear azido mediators, [Co-2(trz)(3)(N-3)](n) 1 (trz(-) = 1,2,4-triazolate), was hydrothermally synthesized and structurally and magnetically characterized. 1 crystallizes in the rhombohedral P6(3)/mmc space group with a = b 10.0716(17), c = 7.5860(14) angstrom, V= 666.4(2) angstrom(3), D-c = 1.814 g/cm(3), M-r = 364.09, Z = 2, F(000) = 360, mu = 2.499 mm(-1), the final R = 0.0676 and wR = 0.1952 for 229 observed reflections with I > 2 sigma(I). Complex 1 consists of linear {Co(trz)(3)}(n) chains passing through a C-6 rotation axis, which are interconnected with tetrahedral Co-II ion by mu(3)-trz(-) ligands into a hexagonal three-dimensional antiferromagnetic framework.
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页码：1159 / 1163
页数：5
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