Ruthenium (II) complexes with π expanded ligand having phenylene-ethynylene moiety as sensitizers for dye-sensitized solar cells

被引：19

作者：

Funaki, Takashi ^{[1
]}

Yanagida, Masatoshi ^{[1
]}

Onozawa-Komatsuzaki, Nobuko ^{[1
]}

Kawanishi, Yuji ^{[2
]}

Kasuga, Kazuyuki ^{[1
]}

Sugihara, Hideki ^{[1
]}

机构：

[1] Natl Inst Adv Ind Sci & Technol, Energy Technol Res Inst, Tsukuba, Ibaraki 3058565, Japan

[2] Natl Inst Adv Ind Sci & Technol, Nanotechnol Res Inst, Tsukuba, Ibaraki 3058565, Japan

来源：

SOLAR ENERGY MATERIALS AND SOLAR CELLS | 2009年 / 93卷 / 6-7期

关键词：

Dye-sensitized solar cell; Ruthenium complex; Phenylene-ethynylene; Nanocrystalline TiO2; NANOCRYSTALLINE TIO2 FILMS; TRICARBOXYTERPYRIDYL COMPLEX; CONVERSION; LIGHT; ELECTRICITY; EFFICIENCY;

D O I：

10.1016/j.solmat.2008.09.011

中图分类号：

TE [石油、天然气工业]; TK [能源与动力工程];

学科分类号：

0807 ; 0820 ;

摘要：

Ruthenium(II) complexes by introducing phenylene-ethynylene subunit into a tpy (tpy = 2,2':6',2 ''-terpyridine) ligand were newly synthesized, and their photophysical and photochemical properties were characterized. The molar extinction coefficients of these dyes were larger than that of black dye. The photovoltaic performances of the solar cells based on these synthesizing dyes were investigated under AM 1.5 irradiation (100 mW cm(-2)). The conversion efficiencies of 1a and 1b were 5.7% and 2.4%, respectively. (C) 2008 Elsevier B.V. All rights reserved.

引用

页码：729 / 732

页数：4

共 14 条

[1] A ruthenium complex with superhigh light-harvesting capacity for dye-sensitized solar cells [J].

Chen, Chia-Yuan ;

Wu, Shi-Jhang ;

Wu, Chun-Guey ;

Chen, Jian-Ging ;

Ho, Kuo-Chuan .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (35) :5822-5825

[2] Dye-sensitized solar cells with conversion efficiency of 11.1% [J].

Chiba, Yasuo ;

Islam, Ashraful ;

Watanabe, Yuki ;

Komiya, Ryoichi ;

Koide, Naoki ;

Han, Liyuan .

JAPANESE JOURNAL OF APPLIED PHYSICS PART 2-LETTERS & EXPRESS LETTERS, 2006, 45 (24-28) :L638-L640

[3] Ruthenium(II) tricarboxyterpyridyl complex with a fluorine-substituted β-diketonato ligand for highly efficient dye-sensitized solar cells [J].

Islam, A ;

Chowdhury, FA ;

Chiba, Y ;

Komiya, R ;

Fuke, N ;

Ikeda, N ;

Han, LY .

CHEMISTRY LETTERS, 2005, 34 (03) :344-345

[4] Efficient panchromatic sensitization of nanocrystalline TiO2 films by β-diketonato ruthenium polypyridyl complexes [J].

Islam, A ;

Sugihara, H ;

Yanagida, M ;

Hara, K ;

Fujihashi, G ;

Tachibana, Y ;

Katoh, R ;

Murata, S ;

Arakawa, H .

NEW JOURNAL OF CHEMISTRY, 2002, 26 (08) :966-968

[5] Engineering of a novel ruthenium sensitizer and its application in dye-sensitized solar cells for conversion of sunlight into electricity [J].

Klein, C ;

Nazeeruddin, MK ;

Liska, P ;

Di Censo, D ;

Hirata, N ;

Palomares, E ;

Durrant, JR ;

Grätzel, M .

INORGANIC CHEMISTRY, 2005, 44 (02) :178-180

[6] Engineering of efficient panchromatic sensitizers for nanocrystalline TiO2-based solar cells [J].

Nazeeruddin, MK ;

Péchy, P ;

Renouard, T ;

Zakeeruddin, SM ;

Humphry-Baker, R ;

Comte, P ;

Liska, P ;

Cevey, L ;

Costa, E ;

Shklover, V ;

Spiccia, L ;

Deacon, GB ;

Bignozzi, CA ;

Grätzel, M .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (08) :1613-1624

[7] CONVERSION OF LIGHT TO ELECTRICITY BY CIS-X2BIS(2,2'-BIPYRIDYL-4,4'-DICARBOXYLATE)RUTHENIUM(II) CHARGE-TRANSFER SENSITIZERS (X = CL-, BR-, I-, CN-, AND SCN-) ON NANOCRYSTALLINE TIO2 ELECTRODES [J].

NAZEERUDDIN, MK ;

KAY, A ;

RODICIO, I ;

HUMPHRYBAKER, R ;

MULLER, E ;

LISKA, P ;

VLACHOPOULOS, N ;

GRATZEL, M .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (14) :6382-6390

[8] A LOW-COST, HIGH-EFFICIENCY SOLAR-CELL BASED ON DYE-SENSITIZED COLLOIDAL TIO2 FILMS [J].

OREGAN, B ;

GRATZEL, M .

NATURE, 1991, 353 (6346) :737-740

[9] Novel ruthenium Sensitizers containing functionalized hybrid tetradentate ligands: Synthesis, characterization, and INDO/S analysis [J].

Renouard, T ;

Fallahpour, RA ;

Nazeeruddin, MK ;

Humphry-Baker, R ;

Gorelsky, SI ;

Lever, ABP ;

Gratzel, M .

INORGANIC CHEMISTRY, 2002, 41 (02) :367-378

[10] Efficient photosensitization of nanocrystalline TiO2 films by a new grass of sensitizer:: cis-dithiocyanato bis(4,7-dicarboxy-1,10-phenanthroline)ruthenium(II) [J].

Sugihara, H ;

Singh, LP ;

Sayama, K ;

Arakawa, H ;

Nazeeruddin, MK ;

Grätzel, M .

CHEMISTRY LETTERS, 1998, (10) :1005-1006

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