Update 1 of: Ionic Liquids in Heterocyclic Synthesis. The root paper of this title was published in Chem. Rev. 2008, 108 (6), 2015-2050

被引：108

作者：

Martins, Marcos A. P. ^{[1
]}

Frizzo, Clarissa P. ^{[1
]}

Tier, Aniele Z. ^{[1
]}

Moreira, Dayse N. ^{[1
]}

Zanatta, Nilo ^{[1
]}

Bonacorso, Helio G. ^{[1
]}

机构：

[1] Univ Fed Santa Maria, Nucleo Quim Heterociclos NUQUIMHE, Dept Quim, BR-97105900 Santa Maria, RS, Brazil

来源：

CHEMICAL REVIEWS | 2014年 / 114卷 / 20期

关键词：

ONE-POT SYNTHESIS; SOLVENT-FREE SYNTHESIS; DIELS-ALDER REACTIONS; MICROWAVE-ASSISTED SYNTHESIS; ASYMMETRIC MICHAEL ADDITION; RECYCLABLE CATALYTIC-SYSTEM; INTRAMOLECULAR AZOMETHINE YLIDE; ELECTRON-PARAMAGNETIC-RESONANCE; TRANSFER RADICAL POLYMERIZATION; HIGHLY FUNCTIONALIZED PYRROLES;

D O I：

10.1021/cr500106x

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Heterocycles form by far the largest of the classical divisions of organic chemistry. Moreover, they are of immense importance not only both biologically and industrially but to the functioning of any developed human society as well. Their participation in a wide range of areas cannot be underestimated. The majority of pharmaceutical products that mimic natural products with biological activity are heterocycles. Additionally, ionic liquids (IL) have attracted increasing interest recently in the context of green organic synthesis. Although ionic liquids were initially introduced as alternative green reaction media because of their unique chemical and physical properties of nonvolatility, nonflammability, thermal stability, and controlled miscibility, today they have marched far beyond this boundary, showing their significant role in controlling reactions as solvent or catalysts. The ILs were interacting with solutes via high dipolar and dispersion forces and were also acting as strong hydrogen bond bases.

引用

页码：PR1 / +

页数：2

共 896 条

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