Thermal degradation properties of solid polymer electrolyte (poly(vinyl alcohol) plus phosphoric acid)/methylene blue composites

被引：83

作者：

Somani, PR

Marimuthu, R

Viswanath, AK

Radhakrishnan, S

机构：

[1] Ctr Mat Elect Technol, Photon & Adv Mat Lab, Pune 411008, Maharashtra, India

[2] Natl Chem Lab, Pune 411008, Maharashtra, India

[3] Agasti Theatre, Akole 422601, Maharashtra, India

来源：

POLYMER DEGRADATION AND STABILITY | 2003年 / 79卷 / 01期

关键词：

poly(vinyl alcohol) (PVA); methylene blue (MB); thermal degradation properties; solid polymer electrolyte;

D O I：

10.1016/S0141-3910(02)00240-9

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The thermal stability and degradation of poly(vinyl alcohol) (PVA), PVA + H3PO4 (solid polymer electrolyte, SPE), PVA containing methylene blue (MB) dye and SPE (PVA + H3PO4) + M B were studied by TG/DTA/DTG and DSC techniques. The FTIR and UV-vis study of these materials indicates that MB forms a complex with the polymer by a hydrogen bonding interaction between the -OH group of the polymer and the nitrogen of MB and improves the thermal stability of the polymer. (C) 2002 Elsevier Science Ltd. All rights reserved.

引用

页码：77 / 83

页数：7

共 29 条

[1] A COMPARISON OF THE THERMAL-DEGRADATION BEHAVIORS OF POLYVINYL ACETATE), POLYVINYL-ALCOHOL) AND POLYVINYL-CHLORIDE) [J].