5-[1-(3,4-Dichlorophenoxy)ethyl]-1,3,4-oxadiazole-2(3H)-thione hemihydrate

被引:2
作者
Akhtar, Tashfeen [1 ]
Rauf, M. Khawar [1 ]
Hameed, Shahid [1 ]
Lu, Xiaoming [2 ]
机构
[1] Quaid I Azam Univ, Dept Chem, Islamabad 45320, Pakistan
[2] Capital Normal Univ, Dept Chem, Beijing Taiyuan 100037, Peoples R China
来源
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2009年 / 65卷
关键词
1,3,4-OXADIAZOLE-2-THIONE DERIVATIVES; 1,2,4-TRIAZOLES;
D O I
10.1107/S1600536809029894
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title compound, C10H8Cl2N2O2S center dot 0.5H(2)O, the atoms in the oxadiazole ring are essentially coplanar (r.m.s. deviation 0.010 angstrom). The crystal structure is stabilized by intermolecular N-H center dot center dot center dot O hydrogen bonds involving the water molecule, which is situated on an a twofold rotation axis, and two organic molecules, leading to a thione tautomer in the solid state. The C atom attached to the oxadiazole ring adopts a typical sp(3) hybridization. The dihedral angle between the mean plane of the benzene ring of the dichlorophenyl group and the mean plane of the oxadiazole ring is 74.18 (4)degrees. The crystal structure is stabilized by intermolecular N-H center dot center dot center dot O and O-H center dot center dot center dot S hydrogen bonds.
引用
收藏
页码:O2075 / O2076
页数:2
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