Dynamic Self-Assembly Encodes A Tri-stable Au-TiO2 Photocatalyst

被引:57
|
作者
Zhang, Qi [1 ,2 ]
Wang, Wen-Zhi [1 ,2 ]
Yu, Jing-Jing [1 ,2 ]
Qu, Da-Hui [1 ,2 ]
Tian, He [1 ,2 ]
机构
[1] East China Univ Sci & Technol, Key Lab Adv Mat, Sch Chem & Mol Engn, 130 Meilong Rd, Shanghai 200237, Peoples R China
[2] East China Univ Sci & Technol, Inst Fine Chem, Sch Chem & Mol Engn, 130 Meilong Rd, Shanghai 200237, Peoples R China
关键词
PARTICLE-SIZE; NANOPARTICLES; METAL; MECHANISMS; CATALYSIS; SURFACE; NANOCOMPOSITES; CONSTRUCTION; COMPLEXATION; POLYMERS;
D O I
10.1002/adma.201604948
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A tri-stable switchable catalyst is encoded by pH-controlled dynamic self-assembly of gold and TiO2 nanoparticles (NPs). Through precise adjustment of the integrated dynamic covalent and noncovalent self-assembly process of the two types of nanoparticles, the photocatalytic activity of the hybrid system is modulated by switching pH conditions between tristable "highly active", "active", and "inactive" states.
引用
收藏
页数:7
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