The Bu4NI-catalyzed alfa-acyloxylation of ketones with benzylic alcohols

被引：80

作者：

Guo, Songjin ^{[1
]}

Yu, Jin-Tao ^{[1
]}

Dai, Qiang ^{[1
]}

Yang, Haitao ^{[1
]}

Cheng, Jiang ^{[1
,2
]}

机构：

[1] Changzhou Univ, Sch Petrochem Engn, Jiangsu Key Lab Adv Catalyt Mat & Technol, Changzhou 213164, Peoples R China

[2] Nanjing Univ, State Key Lab Coordinat Chem, Nanjing 210093, Jiangsu, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 47期

基金：

中国国家自然科学基金;

关键词：

METAL-FREE; CARBONYL-COMPOUNDS; BUTYL HYDROPEROXIDE; EFFICIENT SYNTHESIS; CARBOXYLIC-ACIDS; ESTERIFICATION; OXIDATION; ALDEHYDES; ESTERS; BENZOYLOXYLATION;

D O I：

10.1039/c4cc01652a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The Bu4NI-catalyzed reaction of ketones with benzylic alcohols was achieved, leading to alfa-acyloxycarbonyl compounds in moderate to good yields. This metal-free procedure featured the employment of facilely and commercially available starting materials and TBHP as a clean oxidant with high atom economy.

引用

页码：6240 / 6242

页数：3

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