Amine hardeners and epoxy cross-linker from aromatic renewable resources

被引：81

作者：

Fache, Maxence ^{[1
]}

Monteremal, Camille ^{[1
]}

Boutevin, Bernard ^{[1
]}

Caillol, Sylvain ^{[1
]}

机构：

[1] ENSCM, Inst Charles Gerhardt, Equipe Ingn & Architectures Macromol, CNRS,UMR 5253, F-34296 Montpellier, France

来源：

EUROPEAN POLYMER JOURNAL | 2015年 / 73卷

关键词：

Amine hardener; Vanillin; Furfural; Bio-based; Epoxy; BISPHENOL-A; DIGLYCIDYL ETHER; VANILLIN; DIAMINES; POLYMERS; MONOMERS; ADHESION; RESINS; ACID;

D O I：

10.1016/j.eurpolymj.2015.10.032

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Bio-based epoxy thermosets are currently extensively investigated. To be industrially relevant, bio-based epoxy formulations must be tailored so that the properties of the resulting thermosets can be conveniently controlled. This can be achieved by choosing the right hardener. Amine hardeners were thus synthesized from potentially bio-sourced vanillin and furfural. These compounds are also aromatic, an important structural feature to reach good thermo-mechanical properties. A tri-functional, vanillin-derived epoxy cross-linker was also synthesized. Multi-functional epoxy monomers can increase the cross-linking density of the network, which is another convenient way of controlling the final properties. Epoxy thermosets were prepared from bio-based epoxy monomers and hardeners, as well as from reference compounds commonly used in industry. These polymers were characterized and structure-property relationships are discussed. (C) 2015 Elsevier Ltd. All rights reserved.

引用

页码：344 / 362

页数：19

共 43 条

[31]

Pham H.Q, 2002, ENCY POLYM SCI TECHN

[32]

Pinto P.C. R., 2012, Biomass Conversion, P381, DOI DOI 10.1007/978-3-642-28418-2_12

[33] BISPHENOL-A SYNTHESIS - KINETICS OF PHENOL-ACETONE CONDENSATION REACTION CATALYZED BY SULFONIC-ACID RESIN [J].

REINICKER, RA ;

GATES, BC .

AICHE JOURNAL, 1974, 20 (05) :933-940

[34] THE SPECTROPHOTOMETRIC DETERMINATION OF THE IONIZATION CONSTANTS OF A DIBASIC ACID [J].

ROBINSON, RA ;

KIANG, AK .

TRANSACTIONS OF THE FARADAY SOCIETY, 1956, 52 (03) :327-331

[35] Evaluation of epoxy resins synthesized from steam-exploded bamboo lignin [J].

Sasaki, Chizuru ;

Wanaka, Mio ;

Takagi, Hitoshi ;

Tamura, Satoshi ;

Asada, Chikako ;

Nakamura, Yoshitoshi .

INDUSTRIAL CROPS AND PRODUCTS, 2013, 43 :757-761

[36] NEW METHOD FOR THE SYNTHESIS OF DIFURANIC DIAMINES AND TETRAFURANIC TETRAAMINES [J].

SKOUTA, M ;

LESIMPLE, A ;

LEBIGOT, Y ;

DELMAS, M .

SYNTHETIC COMMUNICATIONS, 1994, 24 (18) :2571-2576

[37] Plant oil-based epoxy resins from fatty diamines and epoxidized vegetable oil [J].

Stemmelen, Mylene ;

Lapinte, Vincent ;

Habas, Jean-Pierre ;

Robin, Jean-Jacques .

EUROPEAN POLYMER JOURNAL, 2015, 68 :536-545

[38] A GENERALIZED THEORY FOR THE GLASS-TRANSITION TEMPERATURE OF CROSS-LINKED AND UNCROSSLINKED POLYMERS [J].

STUTZ, H ;

ILLERS, KH ;

MERTES, J .

JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 1990, 28 (09) :1483-1498

[39] Renewable Rigid Diamines: Efficient, Stereospecific Synthesis of High Purity Isohexide Diamines [J].

Thiyagarajan, Shanmugam ;

Gootjes, Linda ;

Vogelzang, Willem ;

van Haveren, Jacco ;

Lutz, Martin ;

van Es, Daan S. .

CHEMSUSCHEM, 2011, 4 (12) :1823-1829

[40] RECENT ADVANCES WITH GLYCIDYLAMINE RESINS [J].

THOSEBY, MR ;

DOBINSON, B ;

BULL, CH .

BRITISH POLYMER JOURNAL, 1986, 18 (05) :286-291

← 1 2 3 4 5 →