Selective reduction of carbonyl groups in the presence of low-valent titanium reagents

被引：18

作者：

Lin, Wei ^{[1
]}

Hu, Ming-Hua ^{[1
]}

Feng, Xian ^{[1
]}

Fu, Lei ^{[1
]}

Cao, Cheng-Pao ^{[1
]}

Huang, Zhi-Bin ^{[1
]}

Shi, Da-Qing ^{[1
]}

机构：

[1] Soochow Univ, Coll Chem Chem Engn & Mat Sci, Key Lab Organ Synth Jiangsu Prov, Suzhou 215123, Peoples R China

来源：

TETRAHEDRON LETTERS | 2014年 / 55卷 / 14期

关键词：

Chemoselective reduction; Carbonyl groups; Low-valent titanium reagent; HIGHLY REGIOSELECTIVE SYNTHESIS; EFFICIENT SYNTHESIS; CHEMOSELECTIVE REDUCTION; TRANSFER HYDROGENATION; UNSATURATED-KETONES; AID; DERIVATIVES; COMPLEXES; ALDEHYDES; HYDROSILYLATION;

D O I：

10.1016/j.tetlet.2014.02.072

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The chemoselective reduction of several structurally diverse compounds containing carbonyl groups was achieved in the presence of low-valent titanium reagents. This novel synthetic method provides easy access to highly selective reduction of carbonyl groups, and possesses several advantages including one-step procedure, convenient manipulation, good to excellent yields, and short reaction times. (C) 2014 Elsevier Ltd. All rights reserved.

引用

页码：2238 / 2242

页数：5

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