Synthesis and electrocatalytic hydrogen evolution performance of Ni-Mo-Cu alloy coating electrode

被引：95
作者：
Xia, Ming [1 ]
Lei, Ting [1 ]
Lv, Ninglei [1 ]
Li, Nianfeng [2 ]
机构：
[1] Cent S Univ, State Key Lab Powder Met, Changsha 410083, Hunan, Peoples R China
[2] Cent S Univ, Xiangya Hosp, Changsha 410008, Hunan, Peoples R China
来源：
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY | 2014年 / 39卷 / 10期
基金：
中国国家自然科学基金;
关键词：
Ni-Mo-Cu coating; Hydrogen evolution reaction; Electrocatalytic activity; Electrolysis; Electrodeposition; ELECTROCHEMICAL DEPOSITION; ALKALINE; KINETICS; CATHODE; MOLYBDENUM; BEHAVIOR; NICKEL;
D O I：
10.1016/j.ijhydene.2014.01.091
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Ni-Mo-Cu alloy coating electrode was prepared on copper substrate by constant current electrodeposition and characterized by scanning electron microscopy (SEM) and X-ray diffractometry (XRD). The electrochemical characterization for hydrogen evolution reaction (HER) was investigated by cyclic voltammetry (CV) curves, linear sweep voltammetry (LSV) curves and electrochemical impedance spectroscopy (EIS) techniques. Parameters affecting the electrocatalytic activity for the HER are systematically investigated. Results show the Ni-Mo-Cu coating by the introduction of Cu has a rough and cauliflower-like structure and presents a most efficient activity for HER in comparison with binary Ni Mo electrode. Its remarkably enhanced catalytic activity is attributed to the high surface area as well as synergistic interaction between Ni, Mo and Cu. Copyright (C) 2014, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码：4794 / 4802
页数：9
相关论文
共 28 条
[11]   Influence of the work function on electron transfer processes at metals: Application to the hydrogen evolution reaction [J].
Harinipriya, S ;
Sangaranarayanan, MV .
LANGMUIR, 2002, 18 (14) :5572-5578
[12]   Assessment of the roughness factor effect and the intrinsic catalytic activity for hydrogen evolution reaction on Ni-based electrodeposits [J].
Herraiz-Cardona, I. ;
Ortega, E. ;
Garcia Anton, J. ;
Perez-Herranz, V. .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2011, 36 (16) :9428-9438
[13]   Kinetics and electrocatalytic behavior of nanocrystalline CoNiFe alloy in hydrogen evolution reaction [J].
Jafarian, M. ;
Azizi, O. ;
Gobal, F. ;
Mahjani, M. G. .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2007, 32 (12) :1686-1693
[14]   Kinetics of hydrogen evolution reaction on skeleton nickel and nickel-titanium electrodes obtained by thermal arc spraying technique [J].
Kellenberger, Andrea ;
Vaszilcsin, Nicolae ;
Brandl, Waltraut ;
Duteanu, Narcis .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2007, 32 (15) :3258-3265
[15]   Fabrication of porous Co-Ni-P catalysts by electrodeposition and their catalytic characteristics for the generation of hydrogen from an alkaline NaBH4 solution [J].
Kim, Deog-Ryung ;
Cho, Keun-Woo ;
Choi, Yun-Il ;
Park, Chan-Jin .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2009, 34 (06) :2622-2630
[16]   Electrodeposition of Ni-Mo alloy coatings and their characterization as cathodes for hydrogen evolution in sodium hydroxide solution [J].
Krstajic, N. V. ;
Jovic, V. D. ;
Gajic-Krstajic, Lj ;
Jovic, B. M. ;
Antozzi, A. L. ;
Martelli, G. N. .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2008, 33 (14) :3676-3687
[17]  
Lasia A., 2003, Handbook of Fuel Cell Technology, V2, P414, DOI [10.1002/9780470974001.F204033, DOI 10.1002/9780470974001.F204033]
[18]   Electrocatalytic evolution of hydrogen on porous alumina/gelcast-derived nano-carbon network composite electrode [J].
Liu, Jingjun ;
Watanabe, Hideo ;
Fuji, Masayoshi ;
Takahashi, Minoru .
ELECTROCHEMISTRY COMMUNICATIONS, 2009, 11 (01) :107-110
[19]   Characterization of Ni, NiMo, NiW and NiFe electroactive coatings as electrocatalysts for hydrogen evolution in an acidic medium [J].
Navarro-Flores, E ;
Chong, ZW ;
Omanovic, S .
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2005, 226 (02) :179-197
[20]   Electrochemical performance of hydrogen evolution reaction of Ni-Mo electrodes obtained by mechanical alloying [J].
Rodríguez-Valdez, LM ;
Estrada-Guel, I ;
Almeraya-Calderón, F ;
Neri-Flores, MA ;
Martínez-Villafañe, A ;
Martínez-Sánchez, R .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2004, 29 (11) :1141-1145
123