Highly uniform Ru nanoparticles over N-doped carbon: pH and temperature-universal hydrogen release from water reduction

被引：458

作者：

Wang, Jing ^{[1
]}

Wei, Zhongzhe ^{[1
]}

Mao, Shanjun ^{[1
]}

Li, Haoran ^{[1
]}

Wang, Yong ^{[1
]}

机构：

[1] Zhejiang Univ, Inst Catalysis, ZJU NHU United R&D Ctr, Adv Mat & Catalysis Grp, Hangzhou 310028, Zhejiang, Peoples R China

来源：

ENERGY & ENVIRONMENTAL SCIENCE | 2018年 / 11卷 / 04期

基金：

国家重点研发计划; 中国国家自然科学基金;

关键词：

TRANSITION-METAL CARBIDES; HIGH CATALYTIC-ACTIVITY; REDUCED GRAPHENE OXIDE; ACTIVE EDGE SITES; EVOLUTION REACTION; GRAPHITIC CARBON; MOS2; NANOSHEETS; 2-PHENYL-4-(1-NAPHTHYL)QUINOLINIUM ION; EFFICIENT ELECTROCATALYST; BIFUNCTIONAL CATALYST;

D O I：

10.1039/c7ee03345a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Highly uniform ruthenium (Ru) nanoparticles over N-doped carbon (Ru@CN) was designed and confirmed as a promising candidate for the hydrogen evolution reaction (HER) over a wide pH range. In particular, outstanding catalytic activity with an overpotential of 32 mV at 10 mA cm(-2) was achieved in basic media. Moreover, Ru@CN holds promise for hydrogen production from 0 degrees C to 60 degrees C, greatly broadening its applicability.

引用

页码：800 / 806

页数：7

共 69 条

[11] Trimetallic TriStar Nanostructures: Tuning Electronic and Surface Structures for Enhanced Electrocatalytic Hydrogen Evolution [J].

Du, Nana ;

Wang, Chengming ;

Wang, Xijun ;

Lin, Yue ;

Jiang, Jun ;

Xiong, Yujie .

ADVANCED MATERIALS, 2016, 28 (10) :2077-+

[12] Porous C3N4 Nanolayers@N-Graphene Films as Catalyst Electrodes for Highly Efficient Hydrogen Evolution [J].

Duan, Jingjing ;

Chen, Sheng ;

Jaroniec, Mietek ;

Qiao, Shi Zhang .

ACS NANO, 2015, 9 (01) :931-940

[13] Elucidating Hydrogen Oxidation/Evolution Kinetics in Base and Acid by Enhanced Activities at the Optimized Pt Shell Thickness on the Ru Core [J].

Elbert, Katherine ;

Hu, Jue ;

Ma, Zhong ;

Zhang, Yu ;

Chen, Guangyu ;

An, Wei ;

Liu, Ping ;

Isaacs, Hugh S. ;

Adzic, Radoslav R. ;

Wang, Jia X. .

ACS CATALYSIS, 2015, 5 (11) :6764-6772

[14] A New Class of Electrocatalysts for Hydrogen Production from Water Electrolysis: Metal Monolayers Supported on Low-Cost Transition Metal Carbides [J].

Esposito, Daniel V. ;

Hunt, Sean T. ;

Kimmel, Yannick C. ;

Chen, Jingguang G. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (06) :3025-3033

[15] Monolayer platinum supported on tungsten carbides as low-cost electrocatalysts: opportunities and limitations [J].

Esposito, Daniel V. ;

Chen, Jingguang G. .

ENERGY & ENVIRONMENTAL SCIENCE, 2011, 4 (10) :3900-3912

[16] Computational high-throughput screening of electrocatalytic materials for hydrogen evolution [J].

Greeley, Jeff ;

Jaramillo, Thomas F. ;

Bonde, Jacob ;

Chorkendorff, I. B. ;

Norskov, Jens K. .

NATURE MATERIALS, 2006, 5 (11) :909-913

[17] Activating earth-abundant electrocatalysts for efficient, low-cost hydrogen evolution/oxidation: sub-monolayer platinum coatings on titanium tungsten carbide nanoparticles [J].

Hunt, Sean T. ;

Milina, Maria ;

Wang, Zhenshu ;

Roman-Leshkov, Yuriy .

ENERGY & ENVIRONMENTAL SCIENCE, 2016, 9 (10) :3290-3301

[18] High Catalytic Activity of Nitrogen and Sulfur Co-Doped Nanoporous Graphene in the Hydrogen Evolution Reaction [J].

Ito, Yoshikazu ;

Cong, Weitao ;

Fujita, Takeshi ;

Tang, Zheng ;

Chen, Mingwei .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2015, 54 (07) :2131-2136

[19] A Cost-Effective 3D Hydrogen Evolution Cathode with High Catalytic Activity: FeP Nanowire Array as the Active Phase [J].

Jiang, Ping ;

Liu, Qian ;

Liang, Yanhui ;

Tian, Jingqi ;

Asiri, Abdullah M. ;

Sun, Xuping .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2014, 53 (47) :12855-12859

[20] In situ Cobalt-Cobalt Oxide/N-Doped Carbon Hybrids As Superior Bifunctional Electrocatalysts for Hydrogen and Oxygen Evolution [J].

Jin, Haiyan ;

Wang, Jing ;

Su, Diefeng ;

Wei, Zhongzhe ;

Pang, Zhenfeng ;

Wang, Yong .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2015, 137 (07) :2688-2694

← 1 2 3 4 5 6 7 →