Highly uniform Ru nanoparticles over N-doped carbon: pH and temperature-universal hydrogen release from water reduction

被引：458
作者：
Wang, Jing [1 ]
Wei, Zhongzhe [1 ]
Mao, Shanjun [1 ]
Li, Haoran [1 ]
Wang, Yong [1 ]
机构：
[1] Zhejiang Univ, Inst Catalysis, ZJU NHU United R&D Ctr, Adv Mat & Catalysis Grp, Hangzhou 310028, Zhejiang, Peoples R China
来源：
ENERGY & ENVIRONMENTAL SCIENCE | 2018年 / 11卷 / 04期
基金：
国家重点研发计划; 中国国家自然科学基金;
关键词：
TRANSITION-METAL CARBIDES; HIGH CATALYTIC-ACTIVITY; REDUCED GRAPHENE OXIDE; ACTIVE EDGE SITES; EVOLUTION REACTION; GRAPHITIC CARBON; MOS2; NANOSHEETS; 2-PHENYL-4-(1-NAPHTHYL)QUINOLINIUM ION; EFFICIENT ELECTROCATALYST; BIFUNCTIONAL CATALYST;
D O I：
10.1039/c7ee03345a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Highly uniform ruthenium (Ru) nanoparticles over N-doped carbon (Ru@CN) was designed and confirmed as a promising candidate for the hydrogen evolution reaction (HER) over a wide pH range. In particular, outstanding catalytic activity with an overpotential of 32 mV at 10 mA cm(-2) was achieved in basic media. Moreover, Ru@CN holds promise for hydrogen production from 0 degrees C to 60 degrees C, greatly broadening its applicability.
引用
收藏
页码：800 / 806
页数：7
相关论文
共 69 条
[1]   Cathodic activation of titanium-supported gold nanoparticles: An efficient and stable electrocatalyst for the hydrogen evolution reaction [J].
Amin, Mohammed A. ;
Fadlallah, Sahar A. ;
Alosaimi, Ghaida S. ;
Kandemirli, Fatma ;
Saracoglu, Murat ;
Szunerits, Sabine ;
Boukherroub, Rabah .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2016, 41 (15) :6326-6341
[2]   Surface Polarization Matters: Enhancing the Hydrogen-Evolution Reaction by Shrinking Pt Shells in Pt-Pd-Graphene Stack Structures [J].
Bai, Song ;
Wang, Chengming ;
Deng, Mingsen ;
Gong, Ming ;
Bai, Yu ;
Jiang, Jun ;
Xiong, Yujie .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2014, 53 (45) :12120-12124
[3]   Ni/nitrogen-doped graphene nanotubes acted as a valuable tailor for remarkably enhanced hydrogen evolution performance of platinum-based catalysts [J].
Bao, Xiaobing ;
Wang, Jing ;
Lian, Xu ;
Jin, Haiyan ;
Wang, Shiping ;
Wang, Yong .
JOURNAL OF MATERIALS CHEMISTRY A, 2017, 5 (31) :16249-16254
[4]   Palladium Nanoparticle-Graphitic Carbon Nitride Porous Synergistic Catalyst for Hydrogen Evolution/Oxidation Reactions over a Broad Range of pH and Correlation of Its Catalytic Activity with Measured Hydrogen Binding Energy [J].
Bhowmik, Tanmay ;
Kundu, Manas Kumar ;
Barman, Sudip .
ACS CATALYSIS, 2016, 6 (03) :1929-1941
[5]   Highly active and durable nanostructured molybdenum carbide electrocatalysts for hydrogen production [J].
Chen, W. -F. ;
Wang, C. -H. ;
Sasaki, K. ;
Marinkovic, N. ;
Xu, W. ;
Muckerman, J. T. ;
Zhu, Y. ;
Adzic, R. R. .
ENERGY & ENVIRONMENTAL SCIENCE, 2013, 6 (03) :943-951
[6]   Hydrogen-Evolution Catalysts Based on Non-Noble Metal Nickel-Molybdenum Nitride Nanosheets [J].
Chen, Wei-Fu ;
Sasaki, Kotaro ;
Ma, Chao ;
Frenkel, Anatoly I. ;
Marinkovic, Nebojsa ;
Muckerman, James T. ;
Zhu, Yimei ;
Adzic, Radoslav R. .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2012, 51 (25) :6131-6135
[7]   Optically transparent hydrogen evolution catalysts made from networks of copper-platinum core-shell nanowires [J].
Chen, Zuofeng ;
Ye, Shengrong ;
Wilson, Adria R. ;
Ha, Yoon-Cheol ;
Wiley, Benjamin J. .
ENERGY & ENVIRONMENTAL SCIENCE, 2014, 7 (04) :1461-1467
[8]   Superior performance of borocarbonitrides, BxCyNz, as stable, low-cost metal-free electrocatalysts for the hydrogen evolution reaction [J].
Chhetri, Manjeet ;
Maitra, Somak ;
Chakraborty, Himanshu ;
Waghmare, Umesh V. ;
Rao, C. N. R. .
ENERGY & ENVIRONMENTAL SCIENCE, 2016, 9 (01) :95-101
[9]   Biomass-derived carbon: synthesis and applications in energy storage and conversion [J].
Deng, Jiang ;
Li, Mingming ;
Wang, Yong .
GREEN CHEMISTRY, 2016, 18 (18) :4824-4854
[10]   Alternative energy technologies [J].
Dresselhaus, MS ;
Thomas, IL .
NATURE, 2001, 414 (6861) :332-337
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