2-Quinoxalinol diamine Cu(II) complex: facilitating catalytic oxidation through dual mechanisms

被引：9

作者：

Li, Yuancheng ^{[1
]}

Lee, TaeBum ^{[1
]}

Weerasiri, Kushan ^{[1
]}

Wang, Tanyu ^{[1
]}

Buss, Emily E. ^{[1
]}

McKee, Michael L. ^{[1
]}

Gorden, Anne E. V. ^{[1
]}

机构：

[1] Auburn Univ, Dept Chem & Biochem, Auburn, AL 36849 USA

来源：

DALTON TRANSACTIONS | 2014年 / 43卷 / 36期

关键词：

TERT-BUTYL HYDROPEROXIDE; ALLYLIC OXIDATION; DIRHODIUM CAPROLACTAMATE; ACETATE; KETONES; WATER;

D O I：

10.1039/c4dt01562b

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The Cu(II) complex 1, Cu(II)-6-N-3,5-di-tert-butylsalicylidene-6,7-quinoxalinol-diamine, has been developed to address problems with current methods of catalytic oxidation using tert-butyl hydroperoxide (TBHP). Complex 1 demonstrated an increased capability to utilize TBHP while limiting interference from free radical reactions and was demonstrated to be highly effective in the oxidations of a variety of olefins.

引用

页码：13578 / 13583

页数：6

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