The second chemiluminescence emission of luminol-periodate-menadione sodium bisulfite system and its analytical application

被引：18

作者：

Li, Baoxin ^{[1
]}

Zhang, Xiaoyan

Zhang, Chengxiao

机构：

[1] Shaanxi Normal Univ, Sch Chem & Mat Sci, Dept Chem, Xian 710062, Peoples R China

[2] Air Force Engn Univ, Sch Sci, Xian 710051, Peoples R China

来源：

ANALYTICA CHIMICA ACTA | 2006年 / 575卷 / 02期

基金：

中国国家自然科学基金;

关键词：

second chemiluminescence emission; luminol-periodate; menadione sodium bisulfite; flow-injection analysis;

D O I：

10.1016/j.aca.2006.05.095

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

In this paper, a new chemiluminescence phenomenon described as the second chemiluminescence emission was observed when menadione sodium bisulfite was injected into a reaction mixture of luminol and potassium periodate, in which luminol was oxidized by excess amount of potassium periodate for about 24 h. The mechanism of the second chemiluminescence emission was proposed based a series of experiments. Moreover, our experiment discovered that the second chemiluminescence intensity was a linear function of the concentration of menadione sodium bisulfite in the range of 2 x 10(-9) to 4 x 10(-5) g L-1. Based on this phenomenon, a new flow-injection method for the determination of menadione sodium bisulfite has been established. (c) 2006 Elsevier B.V. All rights reserved.

引用

页码：212 / 216

页数：5

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