A spin-crossover complex based on a 2,6-bis(pyrazol-1-yl) pyridine (1-bpp) ligand functionalized with a carboxylate group

被引：38

作者：

Abherve, Alexandre ^{[1
]}

Clemente-Leon, Miguel ^{[1
]}

Coronado, Eugenio ^{[1
]}

Gomez-Garcia, Carlos J. ^{[1
]}

Lopez-Jorda, Maurici ^{[1
]}

机构：

[1] Univ Valencia, Inst Ciencia Mol ICMol, Paterna 46980, Spain

来源：

DALTON TRANSACTIONS | 2014年 / 43卷 / 25期

关键词：

TRANSITION; TEMPERATURE; LIESST; METAL;

D O I：

10.1039/c4dt00327f

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Combining Fe(II) with the carboxylate-functionalized 2,6-bis(pyrazol-1-yl) pyridine (bppCOOH) ligand results in the spin-crossover compound [Fe(bppCOOH)(2)](ClO4)(2) which shows an abrupt spin transition with a T-1/2 of ca. 380 K and a T-LIESST of 60 K due to the presence of a hydrogen-bonded linear network of complexes.

引用

页码：9406 / 9409

页数：4

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