Fast removal of uranium from aqueous solutions using tetraethylenepentamine modified magnetic chitosan resin

被引：149

作者：

Elwakeel, Khalid Z. ^{[1
]}

Atia, Asem A. ^{[2
]}

Guibal, Eric ^{[3
]}

机构：

[1] Port Said Univ, Fac Sci, Dept Environm Sci, Port Said, Egypt

[2] Menoufia Univ, Fac Sci, Dept Chem, Menoufia, Egypt

[3] Ecole Mines Ales, Ctr Mat Mines Ales, MPA BCI C2MA, F-30319 Ales, France

来源：

BIORESOURCE TECHNOLOGY | 2014年 / 160卷

关键词：

Uranyl ion removal; Kinetics; Thermodynamics; Chitosan derivative; Ferromagnetic sorbent; METAL-IONS; ADSORPTION; PRECIPITATION; SEPARATION; WATER; MERCURY(II); RECOVERY; MEDIA;

D O I：

10.1016/j.biortech.2014.01.037

中图分类号：

S2 [农业工程];

学科分类号：

0828 ;

摘要：

Chitosan was cross-linked using glutaraldehyde in the presence of magnetite. The resin was chemically modified through the reaction with tetraethylenepentamine (TEPA) to produce amine bearing chitosan. The resin showed a higher affinity towards the uptake of UO22+ ions from aqueous medium: maximum sorption capacity reached 1.8 mmol g (1) at pH 4 and 25 degrees C. The nature of interaction of UO22+ ions with the resin was identified. Kinetics were carried out at different temperatures and thermodynamic parameters were evaluated. Breakthrough curves for the removal of UO22+ were studied at different flow rates, bed heights and after 3 regeneration cycles. Hydrochloric acid (0.5 M) was used for desorbing UO22+ from loaded resin: desorption yield as high as 98% was obtained. (C) 2014 Elsevier Ltd. All rights reserved.

引用

页码：107 / 114

页数：8

共 33 条

[1] Studies on the interaction of mercury(II) and uranyl(II) with modified chitosan resins [J].

Atia, AA .

HYDROMETALLURGY, 2005, 80 (1-2) :13-22

[2] Adsorption behaviour of non-transition metal ions on a synthetic chelating resin bearing iminoacetate functions [J].

Atia, AA ;

Donia, AM ;

ELwakeel, KZ .

SEPARATION AND PURIFICATION TECHNOLOGY, 2005, 43 (01) :43-48

[3] Use of BDST and an ANN model for prediction of dye adsorption efficiency of Eucalyptus camaldulensis barks in fixed-bed system [J].

Balci, Behzat ;

Keskinkan, Olcayto ;

Avci, Mutlu .

EXPERT SYSTEMS WITH APPLICATIONS, 2011, 38 (01) :949-956

[4]

Cao Q., 2013, J HAZARD MAT

[5] Selective separation of mercury(II) using magnetic chitosan resin modified with Schiff's base derived from thiourea and glutaraldehyde [J].

Donia, Ahmed M. ;

Atia, Asem A. ;

Elwakeel, Khalid Z. .

JOURNAL OF HAZARDOUS MATERIALS, 2008, 151 (2-3) :372-379

[6] Recovery of gold(III) and silver(I) on a chemically modified chitosan with magnetic properties [J].

Donia, Ahmed M. ;

Atia, Asem A. ;

Elwakeel, Khalid Z. .

HYDROMETALLURGY, 2007, 87 (3-4) :197-206

[7] Synthesis of new ammonium chitosan derivatives and their application for dye removal from aqueous media [J].

Elwakeel, Khalid Z. ;

Abd El-Ghaffar, M. A. ;

El-kousy, Salah M. ;

El-Shorbagy, Hadeel G. .

CHEMICAL ENGINEERING JOURNAL, 2012, 203 :458-468

[8] Removal of Cr(VI) from alkaline aqueous solutions using chemically modified magnetic chitosan resins [J].

Elwakeel, Khalid Z. .

DESALINATION, 2010, 250 (01) :105-112

[9]

Freundlich H, 1906, Z PHYS CHEM-STOCH VE, V57, P385

[10] Interaction of chitosan with metal ions: from environmental applications to the elaboration of new materials [J].

Guibal, E. ;

Vincent, T. ;

Roussy, J. .

BIOHYDROMETALLURGY: A MEETING POINT BETWEEN MICROBIAL ECOLOGY, METAL RECOVERY PROCESSES AND ENVIRONMENTAL REMEDIATION, 2009, 71-73 :519-526

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