Anchoring RuO2 nanoparticles on reduced graphene oxide-multi-walled carbon nanotubes as a high-performance supercapacitor

被引:31
作者
Hosseini, Mir Ghasem [1 ,2 ]
Shahryari, Elham [1 ]
机构
[1] Univ Tabriz, Chem Fac, Dept Phys Chem, Electrochem Res Lab, Tabriz, Iran
[2] Near East Univ, Engn Fac, Dept Mat Sci & Nanotechnol, Mersin 10, TR-99138 Nicosia, North Cyprus, Turkey
基金
美国国家科学基金会;
关键词
Supercapacitor; RuO2; Reduced graphene oxide; Specific capacitance; RUTHENIUM OXIDE; ELECTROCHEMICAL PERFORMANCE; NANOPOROUS CARBON; FACILE SYNTHESIS; ELECTRODE; COMPOSITE; POLYANILINE; NANOCOMPOSITES; FABRICATION; NANOSHEETS;
D O I
10.1007/s11581-018-2668-2
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Herein, we have prepared reduced graphene oxide-multi-walled carbon nanotubes-RuO2 (RGO-MWCNT-RuO2) for supercapacitor applications. For reaching to this purpose, graphene oxide (GO) was reduced with the help of NaBH4 and MWCNT was added to it. Then, RuO2 nanoparticles were decorated on the surfaces of RGO-MWCNT. Different techniques such as field emission scanning electron microscopy (FE-SEM), X-ray diffraction (XRD), thermal gravimetric analysis (TGA), and X-ray photoelectron spectroscopy (XPS) have been used to characterize the as-prepared sample. Electrochemical performance of the electrodes was studied in 1M H2SO4 with different electrochemical techniques such as cyclic voltammetry (CV), charge-discharge (CD), and electrochemical impedance spectroscopy (EIS). RGO-MWCNT-RuO2 electrode showed high specific capacitance of 1846.3Fg(-1) at 10mVs(-1). Meanwhile, this electrode exhibits excellent long cycle life of 98.3% initial specific capacitance retained after 500cycles of charge-discharge at 100Ag(-1). These excellent properties make this nanocomposite as a good candidate for supercapacitor electrodes.
引用
收藏
页码:2383 / 2391
页数:9
相关论文
共 40 条
[1]   Facile synthesis of ultra-small ruthenium oxide nanoparticles anchored on reduced graphene oxide nanosheets for high-performance supercapacitors [J].
Amir, F. Z. ;
Pham, V. H. ;
Dickerson, J. H. .
RSC ADVANCES, 2015, 5 (83) :67638-67645
[2]   Synthesis of a highly efficient 3D graphene-CNT-MnO2-PANI nanocomposite as a binder free electrode material for supercapacitors [J].
Asif, Muhammad ;
Tan, Yi ;
Pan, Lujun ;
Rashad, Muhammad ;
Li, Jiayan ;
Fu, Xin ;
Cui, Ruixue .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2016, 18 (38) :26854-26864
[3]   Highly Dispersed RuO2 Nanoparticles on Carbon Nanotubes: Facile Synthesis and Enhanced Supercapacitance Performance [J].
Bi, Rong-Rong ;
Wu, Xing-Long ;
Cao, Fei-Fei ;
Jiang, Ling-Yan ;
Guo, Yu-Guo ;
Wan, Li-Jun .
JOURNAL OF PHYSICAL CHEMISTRY C, 2010, 114 (06) :2448-2451
[4]   Incorporation of graphene-Mn3O4 core into polyaniline shell: supercapacitor electrode material [J].
Boddula, Rajender ;
Bolagam, Ravi ;
Srinivasan, Palaniappan .
IONICS, 2018, 24 (05) :1467-1474
[5]   A Cr2O3/MWCNTs composite as a superior electrode material for supercapacitor [J].
Chen, Bingwei ;
Wang, Yanfang ;
Li, Chunyang ;
Fu, Lijun ;
Liu, Xiang ;
Zhu, Yusong ;
Zhang, Lixin ;
Wu, Yuping .
RSC ADVANCES, 2017, 7 (40) :25019-25024
[6]   Inexpensive synthesis route of porous polyaniline-ruthenium oxide composite for supercapacitor application [J].
Deshmukh, P. R. ;
Patil, S. V. ;
Bulakhe, R. N. ;
Sartale, S. D. ;
Lokhande, C. D. .
CHEMICAL ENGINEERING JOURNAL, 2014, 257 :82-89
[7]   Nanostructured RuO2 on MWCNTs: Efficient catalyst for transfer hydrogenation of carbonyl compounds and aerial oxidation of alcohols [J].
Gopiraman, M. ;
Babu, S. Ganesh ;
Karvembu, R. ;
Kim, I. S. .
APPLIED CATALYSIS A-GENERAL, 2014, 484 :84-96
[8]   Freestanding Three-Dimensional Graphene/MnO2 Composite Networks As Ultra light and Flexible Supercapacitor Electrodes [J].
He, Yongmin ;
Chen, Wanjun ;
Li, Xiaodong ;
Zhang, Zhenxing ;
Fu, Jiecai ;
Zhao, Changhui ;
Xie, Erqing .
ACS NANO, 2013, 7 (01) :174-182
[9]  
Hosseini M., 2015, INT J NANOSCI NANOTE, V11, P147
[10]   Electrochemical behavior of a Nafion-membrane-based solid-state supercapacitor with a graphene oxide-multiwalled carbon nanotube-polypyrrole nanocomposite [J].
Hosseini, Mir Ghasem ;
Rasouli, Haleh ;
Shahryari, Elham ;
Naji, Leila .
JOURNAL OF APPLIED POLYMER SCIENCE, 2017, 134 (24)