Highly modulated structure and upconversion photoluminescence properties of PbGd2(MoO4)4:Er3+/Yb3+ phosphors

Double molybdate of PbGd2-x(MoO4)(4):Er3+/Yb3+ phosphors with the correct doping concentrations of Er3+ and Yb3+ (x= Er3+ + Yb3+, Er3+ = 0.05, 0.1, 0.2 and Yb3+ = 0.2, 0.45) were successfully synthesized by microwave sol-gel process. The highly modulated structure and the upconversion photoluminescence properties were investigated in detail. The synthesized particles, formed after heat-treatment at 900 degrees C for 16 h, showed a well ctystallized morphology with particle sizes of 2-5 mu m. Under excitation at 980 nm, the PbGd1.7(MoO4)(4):Er(0.1)Ybo(0.2) and PbGd1.5(MoO4)(4):Er0.05Yb0.45 particles exhibited a strong 525-nm emission band, a weak 550-nm emission band in the green region, and a very weak 655-nm emission band in the red region. The Raman spectra of the doped particles indicated the disordered structures of PbGd2-x(MoO4)(4) by the incorporation of the Er3+ and Yb3+ ions into the crystal lattice, which resulted in the highly modulated structure as well as a concentration quenching effect of Er3+ ions. (C) 2015 Published by Elsevier Ltd.