Rhodium(I)-Catalyzed [4+2] Cycloaddition Reactions of 2-Alkylenecyclo-butanols with Alkynes and (E)-2-Nitroethenylbenzene through C(sp2)-C(sp3) Bond Cleavage

被引：3
作者：
Zheng, Xinxin [2 ]
Zhang, Guozhu [1 ]
Zhang, Dayong [2 ]
机构：
[1] Chinese Acad Sci, Shanghai Inst Organ Chem, Ctr Excellence Mol Synth, State Key Lab Organometall Chem, 345 Lingling Rd, Shanghai 200032, Peoples R China
[2] China Pharmaceut Univ, Inst Pharmaceut Sci, Nanjing 210009, Jiangsu, Peoples R China
来源：
CHINESE JOURNAL OF CHEMISTRY | 2019年 / 37卷 / 08期
关键词：
C-C BOND; CARBON-CARBON BOND; DIELS-ALDER REACTIONS; TERT-CYCLOBUTANOLS; SILYLIUM ION; CONSTRUCTION; RHODIUM; ACTIVATION; BETA; CATALYSIS;
D O I：
10.1002/cjoc.201900082
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
An intermolecular [4 + 2] cycloaddition was realized through C-C bond cleavage in the presence of Rh(I) catalyst. The selective ring opening of 2-alkylenecyclobutanols enables the generation of active alkenylrhodium species, which underwent smooth cross addition over alkynes and (E)-2-nitroethenylbenzene, leading to highly substituted all-carbon six-membered rings in a single step and in a complete atom economy.
引用
收藏
页码：786 / 792
页数：7
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