Intra-molecular electronic energy transfer in mono- and di-nuclear zinc(II) supramolecular complexes

被引：11

作者：

Fabbrizzi, L ^{[1
]}

Licchelli, M ^{[1
]}

Marcotte, N ^{[1
]}

Stomeo, F ^{[1
]}

Taglietti, A ^{[1
]}

机构：

[1] Univ Pavia, Dipartimento Chim Gen, I-27100 Pavia, Italy

来源：

SUPRAMOLECULAR CHEMISTRY | 2002年 / 14卷 / 2-3期

关键词：

electronic energy transfer; metal ligand interactions; polyamine ligands; Zn(II) complexes;

D O I：

10.1080/10610270290026022

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Intra-molecular electronic energy transfer processes have been investigated in systems containing two distinct fluorophores Fl(1) (absorbing photonic energy) and Fl(2) (coumarin 343, brought at a close distance through coordinative interactions, emitting). Fl(1) is covalently linked or incorporated in a polyamine platform containing one or two Zn-II, ions, while Fl(2) coordinates the Zn-II centre(s) through a carboxylate group. Zn-II has been chosen for its photophysical inactivity and quick reversibility of the interaction with Fl(2)

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页码：127 / 132

页数：6

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