Hydration of terminal alkynes catalyzed by cobalt corrole complex

被引：16

作者：

Lai, Jia-Wei ^{[1
]}

Liu, Zhao-Yang ^{[1
]}

Chen, Xiao-Yan ^{[1
]}

Zhang, Hao ^{[1
]}

Liu, Hai-Yang ^{[1
]}

机构：

[1] South China Univ Technol, Dept Chem, Key Lab Funct Mol Engn Guangdong Prov, Guangzhou 510640, Peoples R China

来源：

TETRAHEDRON LETTERS | 2020年 / 61卷 / 43期

基金：

中国国家自然科学基金;

关键词：

Cobalt(III) corrole; Hydration; Terminal alkynes; COUNTERION;

D O I：

10.1016/j.tetlet.2020.152426

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Cobalt(III) corrole was firstly applied to the hydration of terminal alkynes. The alkyne hydration proceeded in good to excellent yield with 0.03 to 0.3 mol% cobalt corrole catalyst loading. A wide range of substrates were tolerated. Particularly, the reaction can give 90% yield in a gram scale experiment. (C) 2020 Elsevier Ltd. All rights reserved.

引用

页数：4

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