Hydration of terminal alkynes catalyzed by cobalt corrole complex

被引：16
|
作者：
Lai, Jia-Wei [1 ]
Liu, Zhao-Yang [1 ]
Chen, Xiao-Yan [1 ]
Zhang, Hao [1 ]
Liu, Hai-Yang [1 ]
机构：
[1] South China Univ Technol, Dept Chem, Key Lab Funct Mol Engn Guangdong Prov, Guangzhou 510640, Peoples R China
来源：
TETRAHEDRON LETTERS | 2020年 / 61卷 / 43期
基金：
中国国家自然科学基金;
关键词：
Cobalt(III) corrole; Hydration; Terminal alkynes; COUNTERION;
D O I：
10.1016/j.tetlet.2020.152426
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Cobalt(III) corrole was firstly applied to the hydration of terminal alkynes. The alkyne hydration proceeded in good to excellent yield with 0.03 to 0.3 mol% cobalt corrole catalyst loading. A wide range of substrates were tolerated. Particularly, the reaction can give 90% yield in a gram scale experiment. (C) 2020 Elsevier Ltd. All rights reserved.
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页数：4
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