Conduction type and defect levels of β-FeSi2 films grown by MBE with different Si/Fe ratios

被引:5
作者
Seki, N [1 ]
Takakura, K [1 ]
Suemasu, T [1 ]
Hasegawa, F [1 ]
机构
[1] Univ Tsukuba, Inst Phys Appl, Tsukuba, Ibaraki 3058573, Japan
关键词
iron disilicide; conductivity; Si/Fe ratio; RBS;
D O I
10.1016/j.mssp.2003.07.018
中图分类号
TM [电工技术]; TN [电子技术、通信技术];
学科分类号
0808 ; 0809 ;
摘要
[1 0 0]-oriented beta-FeSi2 films were grown on Si(0 0 1) substrates by molecular beam epitaxy (MBE) with a deposited Si to Fe atomic ratio (Si/Fe ratio) varied from 1.6 to 2.8. It was found that the conduction type of the beta-FeSi2 films changed from p- to n-type between the deposited Si/Fe = 2.4 and 2.8. Rutherford Back scattering (RBS) measurements revealed that the real Si/Fe ratio of beta-FeSi2 is 2.0-2.1 for all the samples after 900degreesC annealing for 14 h, showing that stoichiometry of the grown films is almost satisfied even though the deposited Si/Fe ratio was away from stoichiometry. (C) 2003 Elsevier Ltd. All rights reserved.
引用
收藏
页码:307 / 309
页数:3
相关论文
共 17 条
[1]   Composition dependence of constituent phase of Fe-Si thin film prepared by MOCVD [J].
Akiyama, K ;
Ohya, S ;
Konuma, S ;
Numata, K ;
Funakubo, H .
JOURNAL OF CRYSTAL GROWTH, 2002, 237 (1-4 III) :1951-1955
[2]   OPTICAL-PROPERTIES OF SEMICONDUCTING IRON DISILICIDE THIN-FILMS [J].
BOST, MC ;
MAHAN, JE .
JOURNAL OF APPLIED PHYSICS, 1985, 58 (07) :2696-2703
[3]   Room-temperature 1.56 μm electroluminescence of highly oriented β-FeSi2/Si single heterojunction prepared by magnetron-sputtering deposition [J].
Chu, S ;
Hirohada, T ;
Nakajima, K ;
Kan, H ;
Hiruma, T .
JAPANESE JOURNAL OF APPLIED PHYSICS PART 2-LETTERS & EXPRESS LETTERS, 2002, 41 (11A) :L1200-L1202
[4]   Direct growth of [100]-oriented high-quality β-FeSi2 films on Si(001) substrates by molecular beam epitaxy [J].
Hiroi, N ;
Suemasu, T ;
Takakura, K ;
Seki, N ;
Hasegawa, F .
JAPANESE JOURNAL OF APPLIED PHYSICS PART 2-LETTERS, 2001, 40 (10A) :L1008-L1011
[5]  
HONIG RE, 1962, RCA REV, V23, P567
[6]   A silicon/iron-disilicide light-emitting diode operating at a wavelength of 1.5 mu m [J].
Leong, D ;
Harry, M ;
Reeson, KJ ;
Homewood, KP .
NATURE, 1997, 387 (6634) :686-688
[7]   Electroluminescence of β-FeSi2 light emitting devices [J].
Lourenço, MA ;
Butler, TM ;
Kewell, AK ;
Gwilliam, RM ;
Kirkby, KJ ;
Homewood, KP .
JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS SHORT NOTES & REVIEW PAPERS, 2001, 40 (6A) :4041-4044
[8]   POINT-DEFECTS AND THERMOELECTRIC PROPERTIES OF IRON DISILICIDE CERAMICS SINTERED WITH SIH4-PLASMA-PROCESSED MICROGRAINS [J].
MIKI, T ;
MATSUI, Y ;
TERAOKA, Y ;
EBINA, Y ;
MATSUBARA, K ;
KISHIMOTO, K .
JOURNAL OF APPLIED PHYSICS, 1994, 76 (04) :2097-2103
[9]   Characterization of the stoichiometry of coevaporated FeSix films by AES, EDX, RES, and electron microscopy [J].
Schopke, A ;
Selle, B ;
Sieber, I ;
Reinsperger, GU ;
Stauss, P ;
Herz, K ;
Powalla, M .
FRESENIUS JOURNAL OF ANALYTICAL CHEMISTRY, 1997, 358 (1-2) :322-325
[10]   Room temperature 1.6 μm electroluminescence from a Si-based light emitting diode with β-FeSi2 active region [J].
Suemasu, T ;
Negishi, Y ;
Takakura, K ;
Hasegawa, F .
JAPANESE JOURNAL OF APPLIED PHYSICS PART 2-LETTERS, 2000, 39 (10B) :L1013-L1015