Syntheses of new hexacoordinate germanium(IV) complexes.: Crystal structures and properties of [GeCl4(TMEDA)] and [GeCl2(N3)2(TMEDA)]

被引：10
|
作者：
Ejfler, J
Szafert, S
Jiao, HJ
Sobota, P
机构：
[1] Univ Wroclaw, Fac Chem, PL-50383 Wroclaw, Poland
[2] Univ Erlangen Nurnberg, Inst Organ Chem, D-91054 Erlangen, Germany
来源：
NEW JOURNAL OF CHEMISTRY | 2002年 / 26卷 / 06期
关键词：
D O I：
10.1039/b110770b
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The simple high-yield syntheses and some characterization of new hexacoordinate [GeCl4 (TMEDA)] (1) and [GeCl2 (N-3)(2) (TMEDA)] (2) are reported. The crystal structures of neutral 1 and 2 are described. Some electronic, geometrical, and thermodynamic features of 1 and 2 were computationally investigated at the B3LYP density functional level of theory.
引用
收藏
页码：803 / 805
页数：3
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