Syntheses of new hexacoordinate germanium(IV) complexes.: Crystal structures and properties of [GeCl4(TMEDA)] and [GeCl2(N3)2(TMEDA)]

被引：10

作者：

Ejfler, J

Szafert, S

Jiao, HJ

Sobota, P

机构：

[1] Univ Wroclaw, Fac Chem, PL-50383 Wroclaw, Poland

[2] Univ Erlangen Nurnberg, Inst Organ Chem, D-91054 Erlangen, Germany

来源：

NEW JOURNAL OF CHEMISTRY | 2002年 / 26卷 / 06期

关键词：

D O I：

10.1039/b110770b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The simple high-yield syntheses and some characterization of new hexacoordinate [GeCl4 (TMEDA)] (1) and [GeCl2 (N-3)(2) (TMEDA)] (2) are reported. The crystal structures of neutral 1 and 2 are described. Some electronic, geometrical, and thermodynamic features of 1 and 2 were computationally investigated at the B3LYP density functional level of theory.

引用

页码：803 / 805

页数：3

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