Enhanced Thermal Properties for Epoxy Composites with a Three-dimensional Graphene Oxide Filler

被引:25
作者
Gao, Jian [1 ]
Yu, Jinhong [1 ,2 ]
Wu, Xinfeng [3 ]
Rao, Baolin [1 ]
Song, Laifu [1 ]
He, Zihai [1 ]
Lu, Shaorong [1 ]
机构
[1] Guilin Univ Technol, Key Lab New Proc Technol Nonferrous Met & Mat, Minist Educ, Sch Mat Sci & Engn, Guilin 541004, Peoples R China
[2] Chinese Acad Sci, Key Lab Marine Mat & Related Technol, Ningbo Inst Mat Technol & Engn, Ningbo 315201, Zhejiang, Peoples R China
[3] Shanghai Maritime Univ, Coll Ocean Sci & Engn, Shanghai 200240, Peoples R China
基金
中国国家自然科学基金;
关键词
Epoxy; Three-dimensional graphene oxide; Thermal conductivity; CONDUCTIVITY ENHANCEMENT; MECHANICAL-PROPERTIES; RESIN; FUNCTIONALIZATION; NANOCOMPOSITES; COATINGS; PROTECTION;
D O I
10.1007/s12221-015-5637-7
中图分类号
TB3 [工程材料学]; TS1 [纺织工业、染整工业];
学科分类号
0805 ; 080502 ; 0821 ;
摘要
In this study, we report a simple and efficient method to prepare three-dimensional graphene oxide (3DGO) network by freeze drying and investigate the effect of 3DGO network on thermal properties of epoxy composites. It was found that the 3DGO network not only improved thermal conductivity, thermal stability, glass transition temperature and storage modulus of epoxy composites, but also reduced the thermal expansion properties of epoxy composites. For instance, the thermal conductivity value of epoxy composite with only 1.3 wt% 3DGO is 0.62 Wm(-1)K(-1), increased by 148 % in comparison with that of the neat epoxy (0.25 Wm(-1)K(-1)).
引用
收藏
页码:2617 / 2626
页数:10
相关论文
共 46 条
  • [1] Effect of functionalization of graphene nanoplatelets on the mechanical response of graphene/epoxy composites
    Ahmadi-Moghadam, B.
    Sharafimasooleh, M.
    Shadlou, S.
    Taheri, F.
    [J]. MATERIALS & DESIGN, 2015, 66 : 142 - 149
  • [2] Epoxy clay nanocomposites - processing, properties and applications: A review
    Azeez, Asif Abdul
    Rhee, Kyong Yop
    Park, Soo Jin
    Hui, David
    [J]. COMPOSITES PART B-ENGINEERING, 2013, 45 (01) : 308 - 320
  • [3] Superior thermal conductivity of single-layer graphene
    Balandin, Alexander A.
    Ghosh, Suchismita
    Bao, Wenzhong
    Calizo, Irene
    Teweldebrhan, Desalegne
    Miao, Feng
    Lau, Chun Ning
    [J]. NANO LETTERS, 2008, 8 (03) : 902 - 907
  • [4] Quantifying Defects in Graphene via Raman Spectroscopy at Different Excitation Energies
    Cancado, L. G.
    Jorio, A.
    Martins Ferreira, E. H.
    Stavale, F.
    Achete, C. A.
    Capaz, R. B.
    Moutinho, M. V. O.
    Lombardo, A.
    Kulmala, T. S.
    Ferrari, A. C.
    [J]. NANO LETTERS, 2011, 11 (08) : 3190 - 3196
  • [5] Mechanical reinforcement and thermal conductivity in expanded graphene nanoplatelets reinforced epoxy composites
    Chatterjee, S.
    Wang, J. W.
    Kuo, W. S.
    Tai, N. H.
    Salzmann, C.
    Li, W. L.
    Hollertz, R.
    Nueesch, F. A.
    Chu, B. T. T.
    [J]. CHEMICAL PHYSICS LETTERS, 2012, 531 : 6 - 10
  • [6] Interfacial microstructure and its effect on thermal conductivity of SiCp/Cu composites
    Chen, Guoqin
    Yang, Wenshu
    Dong, Ronghua
    Hussain, Murid
    Wu, Gaohui
    [J]. MATERIALS & DESIGN, 2014, 63 : 109 - 114
  • [7] An improved Hummers method for eco-friendly synthesis of graphene oxide
    Chen, Ji
    Yao, Bowen
    Li, Chun
    Shi, Gaoquan
    [J]. CARBON, 2013, 64 : 225 - 229
  • [8] Controlled oxidation level of reduced graphene oxides and its effect on thermoelectric properties
    Choi, Jaeyoo
    Tu, Nguyen D. K.
    Lee, Sang-Soo
    Lee, Hyunjung
    Kim, Jin Sang
    Kim, Heesuk
    [J]. MACROMOLECULAR RESEARCH, 2014, 22 (10) : 1104 - 1108
  • [9] A study on thermal conductivity of electroless Ni-B plated multi-walled carbon nanotubes-reinforced composites
    Choi, Jeong-Ran
    Lee, Young Sil
    Park, Soo-Jin
    [J]. JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY, 2014, 20 (05) : 3421 - 3424
  • [10] Functionalized Graphene Sheet/Polyurethane Nanocomposites: Effect of Particle Size on Physical Properties
    Choi, Jin Taek
    Kim, Dong Hoon
    Ryu, Kwang Sun
    Lee, Hyung-Il
    Jeong, Han Mo
    Shin, Cheol Min
    Kim, Jung Ho
    Kim, Byung Kyu
    [J]. MACROMOLECULAR RESEARCH, 2011, 19 (08) : 809 - 814