Solvent-free microwave-assisted synthesis of imidazo[1,5-a]pyridine and -quinoline derivatives

被引：13

作者：

Herr, Jasmin Martha ^{[1
,2
]}

Roessiger, Carina ^{[1
,2
]}

Albrecht, Georg ^{[2
,3
]}

Yanagi, Hisao ^{[4
]}

Goettlich, Richard ^{[1
,2
]}

机构：

[1] Justus Liebig Univ Giessen, Inst Organ Chem, Heinrich Buff Ring 17, D-35392 Giessen, Germany

[2] Justus Liebig Univ Giessen, Ctr Mat Res LaMa, Giessen, Germany

[3] Justus Liebig Univ Giessen, Inst Appl Phys, Giessen, Germany

[4] NAIST, Dept Mat Sci, Nara, Japan

来源：

SYNTHETIC COMMUNICATIONS | 2019年 / 49卷 / 21期

关键词：

Condensation reaction; microwave reaction; MnO2; imidazo[1; 5-a]pyridine; rearrangement; RATIOMETRIC FLUORESCENT-PROBE; COMPLEXES; EFFICIENT; LIGHT; TRANSANNULATION; ALDEHYDES; EMISSION; LIGANDS; IMIDAZO; SHIFT;

D O I：

10.1080/00397911.2019.1650188

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A quick and highly efficient microwave-assisted preparation of imidazopyridines and -quinolines is described, starting from the corresponding ketones and amines. The method requires no solvent and uses activated MnO2 as an oxidant. A mechanism for the cyclization is proposed and discussed.

引用

页码：2931 / 2940

页数：10

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