Isomerization of 7-Oxabenzonorbornadienes into Naphthols Catalyzed by [RuCl2(CO)3]2

被引：60
作者：
Ballantine, Melissa [1 ]
Menard, Michelle L. [1 ]
Tam, William [1 ]
机构：
[1] Univ Guelph, Guelph Waterloo Ctr Grad Work Chem & Biochem, Dept Chem, Guelph, ON N1G 2W1, Canada
来源：
JOURNAL OF ORGANIC CHEMISTRY | 2009年 / 74卷 / 19期
基金：
加拿大自然科学与工程研究理事会;
关键词：
RING-OPENING REACTIONS; C-ARYL GLYCOSIDES; OXABICYCLIC ALKENES; 2+2 CYCLOADDITION; BICYCLIC ALKENES; ROUTE; AZABENZONORBORNADIENES; REGIOSELECTIVITY; REAGENTS; HALIDES;
D O I：
10.1021/jo901504n
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Ruthenium-catalyzed isomerization of 7-oxanorbornadienes into naphthols was investigated. Among the various ruthenium catalysts tested, [RuCl2(CO)(3)](2) gave the highest yields in the isomerization, and various substituted naphthols were synthesized in moderate to excellent yields. Both symmetrical and Unsymmetrical 7-oxanorbornadienes were employed in the Study, and moderate to excellent regioselectivities were observed.
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收藏
页码：7570 / 7573
页数：4
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