The reactivity of complexes of nickel(0) and platinum(0) containing benzyne and related small-ring alkynes

被引：83
作者：
Bennett, MA
Wenger, E
机构：
[1] Research School of Chemistry, Australian National University, Canberra, ACT 2601
来源：
CHEMISCHE BERICHTE-RECUEIL | 1997年 / 130卷 / 08期
关键词：
nickel; platinum; aryne complexes; cyclohexyne complexes; insertions;
D O I：
10.1002/cber.19971300803
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The preparation and reactivities of cyclohexyne and aryne complexes of platinum(0) and nickel(0) are reviewed. These complexes undergo insertions with unsaturated molecules such as alkenes, alkynes, isocyanides, CO and CO2. In the case of the nickel-benzyne complexes, consecutive insertions are observed with alkynes, leading to substituted naphthalenes with good regioselectivities. A possible mechanism for these double insertions, based on a combination of steric and electronic factors, is discussed in detail.
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页码：1029 / 1042
页数：14
相关论文
共 68 条
[1]   [2.2]paracyclophane-1-yne: Preparation and structural analysis of the bis(triphenylphosphane)platinum complex [J].
Albrecht, K ;
Hockless, DCR ;
Konig, B ;
Neumann, H ;
Bennett, MA ;
deMeijere, A .
CHEMICAL COMMUNICATIONS, 1996, (04) :543-544
[2]   FORMATION OF A RHENIUM BENZYNE DERIVATIVE BY FACILE LIGAND-INDUCED ORTHO-HYDROGEN ABSTRACTION IN A HOMOLEPTIC RHENIUM ARYL - X-RAY CRYSTAL-STRUCTURE OF RE(ETA-2-2-MEC6H3)(2-MEC6H4)2(PME2PH)2 [J].
ARNOLD, J ;
WILKINSON, G ;
HUSSAIN, B ;
HURSTHOUSE, MB .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1988, (11) :704-705
[3]   SYNTHESIS AND REACTIVITY OF BENZYNE DERIVATIVES OF RHENIUM FORMED BY FACILE ORTHO-HYDROGEN ABSTRACTION IN A HOMOLEPTIC RHENIUM ARYL - X-RAY STRUCTURE OF THE CATIONIC BENZYNE [RE(ETA-2-2-MEC6H3)(2-MEC6H4)2(PME3)2][I5] [J].
ARNOLD, J ;
WILKINSON, G ;
HUSSAIN, B ;
HURSTHOUSE, MB .
ORGANOMETALLICS, 1989, 8 (02) :415-420
[4]  
Bennett M. A., 1989, ANGEW CHEM, V101, P1349
[5]   SYNTHESIS AND SINGLE-CRYSTAL X-RAY STUDY OF THE MONONUCLEAR ETA-2-BENZYNE (DEHYDROBENZENE) NICKEL(0) COMPLEX NI(ETA-2-C6H4)((C6H11)2PCH2CH2P(C6H11)2) - INSERTION REACTIONS WITH SIMPLE MOLECULES AND X-RAY CRYSTAL-STRUCTURE OF THE NICKELAINDAN COMPLEX NI(CH2CH2C6H4-O)((C6H11)2PCH2CH2P(C6H11)2) [J].
BENNETT, MA ;
HAMBLEY, TW ;
ROBERTS, NK ;
ROBERTSON, GB .
ORGANOMETALLICS, 1985, 4 (11) :1992-2000
[6]   PREPARATION OF (ORTHO-HALOGENO)-ETA(1)-PYRIDYLNICKEL(II) COMPLEXES, PRECURSORS FOR THE GENERATION OF PYRIDYNE-NICKEL(0) COMPLEXES [J].
BENNETT, MA ;
HOCKLESS, DCR ;
WENGER, E .
POLYHEDRON, 1995, 14 (19) :2637-2645
[7]   STABILIZATION OF 1,2,4,5-TETRADEHYDROBENZENE BY COMPLEXATION AT 2 NICKEL(0) CENTERS [J].
BENNETT, MA ;
DRAGE, JS ;
GRIFFITHS, KD ;
ROBERTS, NK ;
ROBERTSON, GB ;
WICKRAMASINGHE, WA .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1988, 27 (07) :941-942
[8]   THE STABILIZATION AND REACTIVITY OF STRAINED CYCLIC ALKYNES ON TRANSITION-METAL CENTERS [J].
BENNETT, MA .
PURE AND APPLIED CHEMISTRY, 1989, 61 (10) :1695-1700
[9]   INSERTION REACTIONS OF BENZYNE-NICKEL(O) COMPLEXES WITH ACETYLENES [J].
BENNETT, MA ;
WENGER, E .
ORGANOMETALLICS, 1995, 14 (03) :1267-1277
[10]   GENERATION OF (2,3-ETA)-NAPHTHALYNE-NICKEL(0) COMPLEXES AND THEIR REACTIONS WITH UNSATURATED MOLECULES [J].
BENNETT, MA ;
HOCKLESS, DCR ;
WENGER, E .
ORGANOMETALLICS, 1995, 14 (04) :2091-2101
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